N-benzylisopropylidene-iminium tetraphenylborate

Base Information

• Chemical Name: N-benzylisopropylidene-iminium tetraphenylborate
• CAS No.: 185697-08-9
• Molecular Formula: C₁₀H₁₃N*C₂₄H₂₀B*H
• Molecular Weight: 467.462
• Mol file: 185697-08-9.mol

Synonyms:

Chemical Property of N-benzylisopropylidene-iminium tetraphenylborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-benzylisopropylidene-iminium tetraphenylborate

There total 1 articles about N-benzylisopropylidene-iminium tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

C7H9N*C24H20B(1-)*0.5C4H8O*H(1+) + acetone (67-64-1) → N-benzylisopropylidene-iminium tetraphenylborate (185697-08-9)

Guidance literature:

at 20 ℃; for 1.5h; Inert atmosphere; Molecular sieve;

DOI:10.1021/om960602k

Reference yield: 70.0%

[Ni(PCy3)2]2(N2) + N-benzylisopropylidene-iminium tetraphenylborate (185697-08-9) → [trans-(H)Ni(PCy3)2(η1(N)-PhCH2N=CMe2)]BPh4 (185697-06-7)

Guidance literature:

In tetrahydrofuran; N2-atmosphere; stirring (room temp., 5 h); concg., pptn. on Et2O addn. (253 K), filtering, washing (Et2O), drying (vac.), recrystn. (CH2Cl2 / Et2O, 253 K), filtering, washing (Et2O), drying (vac.); elem. anal.;

DOI:10.1021/om960602k

Reference yield: 70.0%

dichloromethane (75-09-2) + N-benzylisopropylidene-iminium tetraphenylborate (185697-08-9) + C72H134N2Ni2P4 → [(H)Ni(PCy3)2(η(1)(N)PhCH2N=CMe2)]BPh4 * CH2Cl2 (185697-07-8)

Guidance literature:

N-benzylisopropylidene-iminium tetraphenylborate; C₇₂H₁₃₄N₂Ni₂P₄; In tetrahydrofuran; at 19.84 ℃; for 5h; Inert atmosphere;

dichloromethane; In diethyl ether; at -20.16 ℃; Inert atmosphere;

DOI:10.1021/om960602k

upstream raw materials:

acetone

Downstream raw materials:

[trans-(H)Ni(PCy3)2(η1(N)-PhCH2N=CMe2)]BPh4

[Pd(1,2-bis(diphenylphosphino)ethane)2](CF₃SO₃)(B(C₆H₅)4)

[HPd(1,2-bis(diphenylphosphino)ethane)2][BPh₄]

[(H)Ni(PCy3)2(η(1)(N)PhCH2N=CMe2)]BPh4 * CH2Cl2