(1'S,2'S,3'R,4'S)-5-[2'-benzyloxy-3'-tert-butyldimethylsilyloxy-4',5'-dihydroxy-1'-(1H-indol-3-yl)-4',5'-di-O-isopropylidene-pentan-1'-yl]-2,2-dimethyl-1,3-dioxane-4,6-dione

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Chemical Name:(1'S,2'S,3'R,4'S)-5-[2'-benzyloxy-3'-tert-butyldimethylsilyloxy-4',5'-dihydroxy-1'-(1H-indol-3-yl)-4',5'-di-O-isopropylidene-pentan-1'-yl]-2,2-dimethyl-1,3-dioxane-4,6-dione
CAS No.:1224111-89-0
Molecular Formula:C₃₅H₄₇NO₈Si
Molecular Weight:637.846
Hs Code.:

(1'S,2'S,3'R,4'S)-5-[2'-benzyloxy-3'-tert-butyldimethylsilyloxy-4',5'-dihydroxy-1'-(1H-indol-3-yl)-4',5'-di-O-isopropylidene-pentan-1'-yl]-2,2-dimethyl-1,3-dioxane-4,6-dione

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Chemical Property of (1'S,2'S,3'R,4'S)-5-[2'-benzyloxy-3'-tert-butyldimethylsilyloxy-4',5'-dihydroxy-1'-(1H-indol-3-yl)-4',5'-di-O-isopropylidene-pentan-1'-yl]-2,2-dimethyl-1,3-dioxane-4,6-dione

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Technology Process of (1'S,2'S,3'R,4'S)-5-[2'-benzyloxy-3'-tert-butyldimethylsilyloxy-4',5'-dihydroxy-1'-(1H-indol-3-yl)-4',5'-di-O-isopropylidene-pentan-1'-yl]-2,2-dimethyl-1,3-dioxane-4,6-dione

There total 1 articles about (1'S,2'S,3'R,4'S)-5-[2'-benzyloxy-3'-tert-butyldimethylsilyloxy-4',5'-dihydroxy-1'-(1H-indol-3-yl)-4',5'-di-O-isopropylidene-pentan-1'-yl]-2,2-dimethyl-1,3-dioxane-4,6-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 120-72-9
indole

: 2033-24-1
cycl-isopropylidene malonate

: 100-39-0
benzyl bromide

: 18162-48-6
tert-butyldimethylsilyl chloride

: 74405-35-9
4,5-O-isopropylidene-L-arabinose di(ethylthio)acetal

: 1224111-89-0
(1'S,2'S,3'R,4'S)-5-[2'-benzyloxy-3'-tert-butyldimethylsilyloxy-4',5'-dihydroxy-1'-(1H-indol-3-yl)-4',5'-di-O-isopropylidene-pentan-1'-yl]-2,2-dimethyl-1,3-dioxane-4,6-dione

: 1224111-90-3
(1'R,2'S,3'R,4'S)-5-[2'-benzyloxy-3'-tert-butyldimethylsilyloxy-4',5'-dihydroxy-1'-(1H-indol-3-yl)-4',5'-di-O-isopropylidene-pentan-1'-yl]-2,2-dimethyl-1,3-dioxane-4,6-dione

: C₃₅H₄₇NO₈Si

: C₃₅H₄₇NO₈Si

Guidance literature:: 4,5-O-isopropylidene-L-arabinose di(ethylthio)acetal; With sodium hydride; In tetrahydrofuran; mineral oil; for 1h;

tert-butyldimethylsilyl chloride; In tetrahydrofuran; mineral oil; at 20 ℃; for 0.5h;

indole; cycl-isopropylidene malonate; benzyl bromide; optical yield given as %de; diastereoselective reaction; Further stages;
DOI:10.1016/j.tetasy.2009.12.017