rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿPr

Base Information

• Chemical Name: rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿPr
• CAS No.: 252868-57-8
• Molecular Formula: C₅₁H₄₃N₄Rh
• Molecular Weight: 814.835

Synonyms:

Chemical Property of rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿPr

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿPr

There total 3 articles about rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿPr which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

chloro(5,10,15,20-tetra-p-tolylporphyrinato)(benzonitrile)rhodium(III) (855308-24-6) + propyl bromide (106-94-5) → rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)nPr (252868-57-8)

Guidance literature:

With sodium hydroxide; sodium tetrahydroborate; In ethanol; 1. NaBH4, EtOH, 50°C, 1 h; 2. RBr, 0°C, 15 min;

DOI:10.1016/j.jorganchem.2007.11.009

Reference yield: 47.0%

tri-n-propylamine (102-69-2) + rhodium(III) tetrakis(4-tolyl)porphyrin chloride (205259-72-9) → rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)nPr (252868-57-8)

Guidance literature:

In further solvent(s); mixt. of Rh complex (0.014 mmol) and nPr3N degassed (3 freeze-pump-thaw cycles), heated under N2 at 120°C for 1 d; solvent evapd. in vac., residue chromd. (silica gel, hexane/CH2Cl2 eluent (1:1));

DOI:10.1016/j.jorganchem.2010.02.007

Reference yield: 12.0%

propan-1-ol (71-23-8) + rhodium(III) tetrakis(4-tolyl)porphyrin chloride (205259-72-9) → rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)nPr (252868-57-8)

Guidance literature:

With potassium carbonate; In benzonitrile; at 120 ℃; for 24h; Inert atmosphere;

DOI:10.1021/acs.organomet.9b00454

upstream raw materials:

chloro(5,10,15,20-tetra-p-tolylporphyrinato)(benzonitrile)rhodium(III)

propyl bromide

tri-n-propylamine

rhodium(III) tetrakis(4-tolyl)porphyrin chloride

Downstream raw materials:

(5,10,15,20-tetrakis-4-tolylporphyrinato)(methyl)rhodium(III)

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 252868-57-8 rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿPr

Send

Send

Metric Ton KG G Pound L ML

Send

Send