[Ni2(PhP(C6H4S-2)2)2(μ-1,2-bis(diphenylphosphanyl)ethane)]

Base Information

Chemical Name:[Ni2(PhP(C6H4S-2)2)2(μ-1,2-bis(diphenylphosphanyl)ethane)]
CAS No.:436154-22-2
Molecular Formula:C₆₂H₅₀Ni₂P₄S₄
Molecular Weight:1164.62
Hs Code.:

Synonyms:

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Chemical Property of [Ni2(PhP(C6H4S-2)2)2(μ-1,2-bis(diphenylphosphanyl)ethane)]

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Technology Process of [Ni2(PhP(C6H4S-2)2)2(μ-1,2-bis(diphenylphosphanyl)ethane)]

There total 3 articles about [Ni2(PhP(C6H4S-2)2)2(μ-1,2-bis(diphenylphosphanyl)ethane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 14647-23-5
1,2-bis(diphenylphosphino)ethane nickel(II) chloride

: 141-52-6
sodium ethanolate

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

: 436154-22-2
Ni2[μ-1,2-bis(diphenylphosphanyl)ethane][PC6H5(C6H4S)2]2

Guidance literature:: In ethanol; soln. of NiCl2dppe and NaOEt added over a period of 10 min to a suspension of PPh(C6H4SH)2 in ethanol under Ar, at room temp.; immediately precipitated solid filtered, washed (ethanol), dried in vacuo; elem. anal.;
DOI:10.1002/1099-0682(200203)2002:4<826::aid-ejic826>3.0.co;2-m

Reference yield:

: 7440-02-0
nickel

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 436154-22-2
[Ni2(PhP(C6H4S-2)2)2(μ-1,2-bis(diphenylphosphanyl)ethane)]

Guidance literature:: With (CH₃)4NClO₄; In acetonitrile; Electrolysis; under N2; soln. of PhP(C6H4SH-2)2 (0.380 mmol) and Ph2P(CH2)2PPh2 (0.380mmol) electrolyzed in the presence of Me4NClO4 using Ni anode (10 mA, 2 h); Ni (21.9 mg) dissolved from anode (E(f) = 0.50 mol/F); elem. anal.;
DOI:10.1002/ejic.200900941

Reference yield:

: 436154-27-7
[NiPC₆H₅(C₆H₄S)2]2

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 436154-22-2
Ni2[μ-1,2-bis(diphenylphosphanyl)ethane][PC6H5(C6H4S)2]2

Guidance literature:: In dichloromethane; 1,2-bis(diphenylphosphanyl)ethane added to a suspension of Ni-complex inCH2Cl2, stirred for 6 h to give clear soln.;; partial evapn. of the solvent and addition of ethanol afforded product;
DOI:10.1002/1099-0682(200203)2002:4<826::aid-ejic826>3.0.co;2-m