copper(I) acetonitrile tris(3-phenylpyrazolyl)phosphine oxide hexafluorophosphate

Base Information

• Chemical Name: copper(I) acetonitrile tris(3-phenylpyrazolyl)phosphine oxide hexafluorophosphate
• CAS No.: 1367554-22-0
• Molecular Formula: C₂₉H₂₄CuN₇OP*F₆P
• Molecular Weight: 726.04
• Mol file: 1367554-22-0.mol

Synonyms:

Chemical Property of copper(I) acetonitrile tris(3-phenylpyrazolyl)phosphine oxide hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of copper(I) acetonitrile tris(3-phenylpyrazolyl)phosphine oxide hexafluorophosphate

There total 1 articles about copper(I) acetonitrile tris(3-phenylpyrazolyl)phosphine oxide hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + tris(3-phenylpyrazolyl)phosphine oxide (1367554-10-6) → copper(I) acetonitrile tris(3-phenylpyrazolyl)phosphine oxide hexafluorophosphate (1367554-22-0)

Guidance literature:

In dichloromethane; under N2; CH2Cl2 added to mixt. of ligand and Cu complex at 20°C;stirred at room temp. for 2 h; solvent evapd.; washed with MTBE; filtered; dried at 70°C;

DOI:10.1021/om300051f

Reference yield:

carbon monoxide (201230-82-2) + copper(I) acetonitrile tris(3-phenylpyrazolyl)phosphine oxide hexafluorophosphate (1367554-22-0) → copper(I) carbonyl tris(3-phenylpyrazolyl)phosphine oxidehexafluorophosphate (1367554-43-5)

Guidance literature:

In dichloromethane; under N2; soln. of Cu complex in degassed CH2Cl2 degassed by three freeze-pump-thaw cycles; filled with CO (1 atm) before third thawing; after thawing, stirred at room temp. overnight; pentane added; solvent removed using cannula filter; solid dried under N2; mixt. of initial and resultant Cu complexes obtained; detd. by (1)H NMR spectra;

DOI:10.1021/om300051f

upstream raw materials:

tetrakis(actonitrile)copper(I) hexafluorophosphate

tris(3-phenylpyrazolyl)phosphine oxide

Downstream raw materials:

copper(I) carbonyl tris(3-phenylpyrazolyl)phosphine oxidehexafluorophosphate