[(N-(1-(4-methoxy-phenyl)-1H-[1,2,3]triazol-4-ylmethyl)-N,N′,N′-tris(pyridin-2-ylmethyl)-ethane-1,2-diamine)FeCl]PF₆

Base Information

• Chemical Name: [(N-(1-(4-methoxy-phenyl)-1H-[1,2,3]triazol-4-ylmethyl)-N,N′,N′-tris(pyridin-2-ylmethyl)-ethane-1,2-diamine)FeCl]PF₆
• CAS No.: 1419074-86-4
• Molecular Formula: C₃₀H₃₂ClFeN₈O*F₆P
• Molecular Weight: 756.901
• Mol file: 1419074-86-4.mol

Synonyms:

Chemical Property of [(N-(1-(4-methoxy-phenyl)-1H-[1,2,3]triazol-4-ylmethyl)-N,N′,N′-tris(pyridin-2-ylmethyl)-ethane-1,2-diamine)FeCl]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(N-(1-(4-methoxy-phenyl)-1H-[1,2,3]triazol-4-ylmethyl)-N,N′,N′-tris(pyridin-2-ylmethyl)-ethane-1,2-diamine)FeCl]PF₆

There total 2 articles about [(N-(1-(4-methoxy-phenyl)-1H-[1,2,3]triazol-4-ylmethyl)-N,N′,N′-tris(pyridin-2-ylmethyl)-ethane-1,2-diamine)FeCl]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

sodium hexaflorophosphate + iron(II) chloride dihydrate + N-(1-(4-methoxy-phenyl)-1H-[1,2,3]triazol-4-ylmethyl)-N,N′,N′-tris(pyridin-2-ylmethyl)-ethane-1,2-diamine (1419075-10-7) → [(N-(1-(4-methoxy-phenyl)-1H-[1,2,3]triazol-4-ylmethyl)-N,N′,N′-tris(pyridin-2-ylmethyl)-ethane-1,2-diamine)FeCl]PF6 (1419074-86-4)

Guidance literature:

In ethanol; Inert atmosphere;

DOI:10.1021/ic301834x

Reference yield:

N1,N1,N2-tris(pyridin-2-ylmethyl)ethane-1,2-diamine (104170-15-2) → [(N-(1-(4-methoxy-phenyl)-1H-[1,2,3]triazol-4-ylmethyl)-N,N′,N′-tris(pyridin-2-ylmethyl)-ethane-1,2-diamine)FeCl]PF6 (1419074-86-4)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium carbonate / tetrahydrofuran / 16 h / 0 - 20 °C / Inert atmosphere

2: copper(ll) sulfate pentahydrate; sodium L-ascorbate / dichloromethane; water / 40 h / 20 °C / Inert atmosphere

3: ethanol / Inert atmosphere

With copper(ll) sulfate pentahydrate; potassium carbonate; sodium L-ascorbate; In tetrahydrofuran; ethanol; dichloromethane; water;

DOI:10.1021/ic301834x

Reference yield:

[(N-(1-(4-methoxy-phenyl)-1H-[1,2,3]triazol-4-ylmethyl)-N,N′,N′-tris(pyridin-2-ylmethyl)-ethane-1,2-diamine)FeCl]PF6 (1419074-86-4) + dihydrogen peroxide (7722-84-1) → [(N-(1-(4-methoxy-phenyl)-1H-[1,2,3]triazol-4-ylmethyl)-N,N′,N′-tris(pyridin-2-ylmethyl)-ethane-1,2-diamine)Fe(OOH)](2+)

Guidance literature:

In methanol; at 0 ℃;

DOI:10.1021/ic301834x

upstream raw materials:

N-(1-(4-methoxy-phenyl)-1H-[1,2,3]triazol-4-ylmethyl)-N,N′,N′-tris(pyridin-2-ylmethyl)-ethane-1,2-diamine

N¹,N¹,N²-tris(pyridin-2-ylmethyl)ethane-1,2-diamine