6-Benzyloxy-5-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-hex-1-en-3-ol

Base Information

Chemical Name:6-Benzyloxy-5-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-hex-1-en-3-ol
CAS No.:88088-65-7
Molecular Formula:C₂₈H₄₁BrO₅Si
Molecular Weight:565.62
Hs Code.:

Synonyms:

Suppliers and Price of 6-Benzyloxy-5-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-hex-1-en-3-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 6-Benzyloxy-5-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-hex-1-en-3-ol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-Benzyloxy-5-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-hex-1-en-3-ol

There total 11 articles about 6-Benzyloxy-5-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-hex-1-en-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2568-24-3
2-phenyl-4,7-dihydro-1,3-dioxepine

: 88088-65-7
6-Benzyloxy-5-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-hex-1-en-3-ol

Guidance literature:: Multi-step reaction with 9 steps

1: 100 percent / LiAlH₄

2: 95.6 percent / PBr₃

3: 88 percent / K₂CO₃ / acetone / Heating

4: 84 percent / N,N-dimethylaniline / 200 °C

5: K₂CO₃ / acetone

6: 1.) KOH; 2.) imidazole / 1.) MeOH, 0 deg C; 2.) DMF

7: 1.) BH₃*SMe₂; 2.) 30 percent H₂O₂, NaOH / 1.) Et₂O, 0 deg C; 2.) EtOH

8: pyridinium chlorochromate / CH₂Cl₂

9: tetrahydrofuran / 0 °C

With 1H-imidazole; potassium hydroxide; sodium hydroxide; lithium aluminium tetrahydride; dimethylsulfide borane complex; dihydrogen peroxide; phosphorus tribromide; potassium carbonate; N,N-dimethyl-aniline; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; acetone;
DOI:10.1246/cl.1983.1383

Reference yield:

: 6971-52-4
3-methoxy-2-methylphenol

: 88088-65-7
6-Benzyloxy-5-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-hex-1-en-3-ol

Guidance literature:: Multi-step reaction with 8 steps

1: Cl₂CHOCH₃

2: 88 percent / K₂CO₃ / acetone / Heating

3: 84 percent / N,N-dimethylaniline / 200 °C

4: K₂CO₃ / acetone

5: 1.) KOH; 2.) imidazole / 1.) MeOH, 0 deg C; 2.) DMF

6: 1.) BH₃*SMe₂; 2.) 30 percent H₂O₂, NaOH / 1.) Et₂O, 0 deg C; 2.) EtOH

7: pyridinium chlorochromate / CH₂Cl₂

8: tetrahydrofuran / 0 °C

With 1H-imidazole; potassium hydroxide; sodium hydroxide; Dichloromethyl methyl ether; dimethylsulfide borane complex; dihydrogen peroxide; potassium carbonate; N,N-dimethyl-aniline; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; acetone;
DOI:10.1246/cl.1983.1383

Reference yield:

: 81028-03-7
(Z)-4-benzyloxy-but-2-en-1-ol

: 88088-65-7
6-Benzyloxy-5-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-hex-1-en-3-ol

Guidance literature:: Multi-step reaction with 8 steps

1: 95.6 percent / PBr₃

2: 88 percent / K₂CO₃ / acetone / Heating

3: 84 percent / N,N-dimethylaniline / 200 °C

4: K₂CO₃ / acetone

5: 1.) KOH; 2.) imidazole / 1.) MeOH, 0 deg C; 2.) DMF

6: 1.) BH₃*SMe₂; 2.) 30 percent H₂O₂, NaOH / 1.) Et₂O, 0 deg C; 2.) EtOH

7: pyridinium chlorochromate / CH₂Cl₂

8: tetrahydrofuran / 0 °C

With 1H-imidazole; potassium hydroxide; sodium hydroxide; dimethylsulfide borane complex; dihydrogen peroxide; phosphorus tribromide; potassium carbonate; N,N-dimethyl-aniline; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; acetone;
DOI:10.1246/cl.1983.1383