dichloro[1,3-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]propane]palladium(II)

Base Information

• Chemical Name: dichloro[1,3-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]propane]palladium(II)
• CAS No.: 609854-36-6
• Molecular Formula: C₃₅H₁₈Cl₂F₂₄P₂Pd
• Molecular Weight: 1133.76
• Mol file: 609854-36-6.mol

Synonyms:

Chemical Property of dichloro[1,3-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]propane]palladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro[1,3-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]propane]palladium(II)

There total 1 articles about dichloro[1,3-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]propane]palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) + 1,3-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]propane (220185-40-0) → dichloro[1,3-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]propane]palladium(II) (609854-36-6)

Guidance literature:

In dichloromethane; under Ar; soln. of (COD)PdCl2 in CH2Cl2 treated with soln. of the bisphosphine ligand in CH2Cl2 and stirred for 1 h; main CH2Cl2 amt. removed by Ar stream; n-pentane added for pptn.; product washed with ether and n-pentane and dried in vacuo; elem. anal.;

DOI:10.1021/om0302138

Reference yield: 68.0%

silver tetrafluoroborate (14104-20-2) + dichloro[1,3-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]propane]palladium(II) (609854-36-6) + acetonitrile (75-05-8,26809-02-9) → diacetonitrile[1,3-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]propane]palladium(II) ditetrafluoroborate

Guidance literature:

In acetonitrile; under Ar; AgBF4 added to soln. of the Pd complex in acetonitrile; soln. stirred for 2 h; soln. filtered, concd. in vacuo, and filtered again; complex pptd. with ether; solid washed with ether and n-pentane and dried in vacuo;

DOI:10.1021/om0302138

upstream raw materials:

dichloro(1,5-cyclooctadiene)palladium(II)

1,3-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]propane