t-butylsulfonyl p-tolylsulfinyl methane

Base Information

• Chemical Name: t-butylsulfonyl p-tolylsulfinyl methane
• CAS No.: 134876-51-0
• Molecular Formula: C₁₂H₁₈O₃S₂
• Molecular Weight: 274.405
• Mol file: 134876-51-0.mol

Synonyms:

Chemical Property of t-butylsulfonyl p-tolylsulfinyl methane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of t-butylsulfonyl p-tolylsulfinyl methane

There total 1 articles about t-butylsulfonyl p-tolylsulfinyl methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert-butyl methyl sulfone (14094-12-3) + methyl p-toluene sulfinate (672-78-6) → t-butylsulfonyl p-tolylsulfinyl methane (134876-51-0)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction; 1.) THF, -78 deg C, 30 min, 2.) RT, 5 h;

DOI:10.1016/S0957-4166(00)80525-X

Reference yield:

t-butylsulfonyl p-tolylsulfinyl methane (134876-51-0) → 1-t-butylsulfonyl-1-p-tolylsulfinylethene (134750-67-7)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol / 3 h / 0 °C

2: MeI, CaCO₃ / acetonitrile / 3 h / Ambient temperature

With calcium carbonate; methyl iodide; In methanol; acetonitrile;

DOI:10.1016/S0957-4166(00)80525-X

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + t-butylsulfonyl p-tolylsulfinyl methane (134876-51-0) + dimethyl amine (124-40-3) → Dimethyl-[2-(2-methyl-propane-2-sulfonyl)-2-(toluene-4-sulfinyl)-ethyl]-amine

Guidance literature:

In methanol; at 0 ℃; for 3h;

DOI:10.1016/S0957-4166(00)80525-X

upstream raw materials:

tert-butyl methyl sulfone

methyl p-toluene sulfinate

Downstream raw materials:

1-t-butylsulfonyl-1-p-tolylsulfinylethene