[ZrCl₂(C₃₀H₂₂)]

Base Information

• Chemical Name: [ZrCl₂(C₃₀H₂₂)]
• CAS No.: 157533-56-7
• Molecular Formula: C₃₀H₂₂Cl₂Zr
• Molecular Weight: 544.635
• Mol file: 157533-56-7.mol

Synonyms:

Chemical Property of [ZrCl₂(C₃₀H₂₂)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [ZrCl₂(C₃₀H₂₂)]

There total 1 articles about [ZrCl₂(C₃₀H₂₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

2-(9-fluorenyl)-1-(1-indenyl)-1-phenylethane (191487-33-9) + zirconium(IV) chloride (10026-11-6) → [ZrCl2(C30H22)] (157533-56-7,157605-15-7)

Guidance literature:

With n-BuLi; In diethyl ether; hexane; toluene; (argon); addn. of n-BuLi in hexane to the ligand in Et2O at 0°C, stirring (30 min), evapn., cooling to -80°C, addn. of toluene andZrCl4, stirring (overnight with warming to room temp.); filtration (Celite), extn. (hot toluene), crystn. (toluene, 4°C);elem. anal.;

DOI:10.1002/cber.19971300612

Reference yield: 79.0%

[ZrCl2(C30H22)] (157533-56-7,157605-15-7) + hydrogen (1333-74-0) → [ZrCl2(C30H40)] (191487-36-2)

Guidance literature:

platinum (IV) oxide hydrate; In dichloromethane; (argon); high-pressure autoclave (125 bar H2, stirring 48 h); filtration (Celite), evapn., crystn. (hexane); elem. anal.;

DOI:10.1002/cber.19971300612

upstream raw materials:

2-(9-fluorenyl)-1-(1-indenyl)-1-phenylethane

zirconium(IV) chloride

Downstream raw materials:

[ZrCl₂(C₃₀H₄₀)]