2,2,5,5,8,8-Hexamethylhexahydrobenzo[1,2-d:3,4-d':5,6-d'']tris[1,3]dioxole

Base Information

Chemical Name:2,2,5,5,8,8-Hexamethylhexahydrobenzo[1,2-d:3,4-d':5,6-d'']tris[1,3]dioxole
CAS No.:90694-04-5
Molecular Formula:C₁₅H₂₄O₆
Molecular Weight:300.352
Hs Code.:
NSC Number:136030,133424
DSSTox Substance ID:DTXSID80299879
Wikidata:Q82042572

Synonyms:90694-04-5;2,2,5,5,8,8-hexamethylhexahydrobenzo[1,2-d:3,4-d':5,6-d'']tris[1,3]dioxole;NSC136030;SCHEMBL7154844;SCHEMBL7155046;SCHEMBL8334423;DTXSID80299879;NSC133424;NSC-133424;NSC-136030

Suppliers and Price of 2,2,5,5,8,8-Hexamethylhexahydrobenzo[1,2-d:3,4-d':5,6-d'']tris[1,3]dioxole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of 2,2,5,5,8,8-Hexamethylhexahydrobenzo[1,2-d:3,4-d':5,6-d'']tris[1,3]dioxole

Chemical Property:

XLogP3:1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:0
Exact Mass:300.15728848
Heavy Atom Count:21
Complexity:357

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(OC2C3C(C4C(C2O1)OC(O4)(C)C)OC(O3)(C)C)C

Technology Process of 2,2,5,5,8,8-Hexamethylhexahydrobenzo[1,2-d:3,4-d':5,6-d'']tris[1,3]dioxole

There total 1 articles about 2,2,5,5,8,8-Hexamethylhexahydrobenzo[1,2-d:3,4-d':5,6-d'']tris[1,3]dioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 116-11-0
2-Methoxypropene

: 87-89-8
D-myo-inositol

: 38643-30-0,40617-60-5,42973-31-9,65556-81-2,96092-79-4,96092-80-7,115116-18-2,115116-20-6
(±)-1,2:5,6-di-O-isopropylidene-myo-inositol

: 51548-88-0,96039-15-5,98974-89-1,128110-25-8
(+/-)-1,2:4,5-di-O-isopropylidene-myo-inositol

: 38643-29-7,90694-04-5,99210-67-0,131564-53-9
1,2:3,4:5,6-tri-O-isopropylidene-myo-inositol

: 38643-30-0,40617-60-5,42973-31-9,65556-81-2,96092-79-4,96092-80-7,115116-18-2,115116-20-6
1,2:3,4-di-O-isopropylidene-myo-inositol

Guidance literature:: With toluene-4-sulfonic acid; In dimethyl sulfoxide; for 22h; Product distribution; Ambient temperature; variation of time, solvent;
DOI:10.1016/0008-6215(90)84052-V

Reference yield:

: 38643-29-7,90694-04-5,99210-67-0,131564-53-9
(+/-)-O¹,O²;O³,O⁴;O⁵,O⁶-triisopropylidene-epi-inositol

: 488-58-4
epi-Inositol

: 38643-30-0,40617-60-5,42973-31-9,65556-81-2,96092-79-4,96092-80-7,115116-18-2,115116-20-6
(+/-)-O¹,O²;O³,O⁴-diisopropylidene-epi-inositol

Guidance literature:: With acetic acid;
DOI:10.1039/jr9520000686

Reference yield:

: 90694-04-5
1L-1,2:3,4:5,6-tri-O-isopropylidene-chiro-inositol

: 1D-(1,2/3,4)-4-azido-1,2-O-isopropylidene-3-O-(4-methoxybenzyl)-5-cyclohexene-1,2,3-triol

Guidance literature:: Multi-step reaction with 6 steps

1.1: 74 percent / camphorsulfonic acid / tetrahydrofuran; methanol / 9 h / 0 °C

2.1: 83 percent / triphenylphosphine; imidazole; iodine / toluene / 1 h / Heating

3.1: 59 percent / Amberlite IR-120 resin (H⁺ form) / tetrahydrofuran; methanol / 12 h / 20 °C

4.1: 92 percent / toluene / 0.67 h / 50 °C

5.1: sodium azide / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran; H₂O / 1 h / 20 °C

6.1: NaH / dimethylformamide / 0.5 h / 0 °C

6.2: 56 percent / dimethylformamide / 2 h / 0 - 20 °C

With 1H-imidazole; sodium azide; Amberlite IR-120 resin (H⁺ form); camphor-10-sulfonic acid; iodine; sodium hydride; triphenylphosphine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; methanol; water; N,N-dimethyl-formamide; toluene; 1.1: Ring cleavage / 2.1: Elimination / 3.1: Ring cleavage / 4.1: Cyclization / 5.1: Ring cleavage / 6.1: Metallation / 6.2: Etherification;
DOI:10.1246/bcsj.71.259