Technology Process of (S)-5-((5E,9E)-(R)-2-Isopropenyl-5,9-dimethyl-11-phenylsulfanyl-undeca-5,9-dienyl)-2,2,4,4-tetramethyl-[1,3]dioxolane
There total 20 articles about (S)-5-((5E,9E)-(R)-2-Isopropenyl-5,9-dimethyl-11-phenylsulfanyl-undeca-5,9-dienyl)-2,2,4,4-tetramethyl-[1,3]dioxolane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 13 steps
1: 2,4-dinitrophenol / toluene / 140 °C
2: Zn(BH4)2
3: Py, DMAP
4: p-TsOH / tetrahydrofuran; H2O
5: NaIO4 / tetrahydrofuran; H2O
6: NaBH4 / methanol
7: 2M aq. NaOH
8: PPTS
9: DEAD, Ph3P, LiI / dimethylformamide
10: dimethylformamide
11: 1.) n-BuLi, 3.) Na(Hg), MeOH / 1.) THF
12: n-Bu4NF
13: Ph3P
With
pyridine; methanol; dmap; sodium hydroxide; sodium tetrahydroborate; sodium periodate; n-butyllithium; 2,4-Dinitrophenol; sodium amalgam; zinc(II) tetrahydroborate; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; toluene-4-sulfonic acid; triphenylphosphine; lithium iodide; diethylazodicarboxylate;
In
tetrahydrofuran; methanol; water; N,N-dimethyl-formamide; toluene;
DOI:10.1246/cl.1996.809
- Guidance literature:
-
Multi-step reaction with 8 steps
1: Et3N
2: K2CO3 / methanol
3: imidazole / dimethylformamide
4: HCOOH / diethyl ether
5: DEAD, Ph3P, LiCl
6: 1.) n-BuLi, 3.) Na(Hg), MeOH / 1.) THF
7: n-Bu4NF
8: Ph3P
With
1H-imidazole; methanol; n-butyllithium; formic acid; sodium amalgam; tetrabutyl ammonium fluoride; potassium carbonate; triethylamine; triphenylphosphine; lithium chloride; diethylazodicarboxylate;
In
methanol; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1246/cl.1996.809
- Guidance literature:
-
Multi-step reaction with 13 steps
1: 2,4-dinitrophenol / toluene / 140 °C
2: Zn(BH4)2
3: Py, DMAP
4: p-TsOH / tetrahydrofuran; H2O
5: NaIO4 / tetrahydrofuran; H2O
6: NaBH4 / methanol
7: 2M aq. NaOH
8: PPTS
9: DEAD, Ph3P, LiI / dimethylformamide
10: dimethylformamide
11: 1.) n-BuLi, 3.) Na(Hg), MeOH / 1.) THF
12: n-Bu4NF
13: Ph3P
With
pyridine; methanol; dmap; sodium hydroxide; sodium tetrahydroborate; sodium periodate; n-butyllithium; 2,4-Dinitrophenol; sodium amalgam; zinc(II) tetrahydroborate; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; toluene-4-sulfonic acid; triphenylphosphine; lithium iodide; diethylazodicarboxylate;
In
tetrahydrofuran; methanol; water; N,N-dimethyl-formamide; toluene;
DOI:10.1246/cl.1996.809
