(5,10,15-tris(2,6-dichlorophenyl)-20-(4-pyridyl)porphyrin)manganese(III) chloride

Base Information

• Chemical Name: (5,10,15-tris(2,6-dichlorophenyl)-20-(4-pyridyl)porphyrin)manganese(III) chloride
• CAS No.: 862801-25-0
• Molecular Formula: C₄₃H₂₁Cl₇MnN₅
• Molecular Weight: 910.782
• Mol file: 862801-25-0.mol

Synonyms:

Chemical Property of (5,10,15-tris(2,6-dichlorophenyl)-20-(4-pyridyl)porphyrin)manganese(III) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (5,10,15-tris(2,6-dichlorophenyl)-20-(4-pyridyl)porphyrin)manganese(III) chloride

There total 1 articles about (5,10,15-tris(2,6-dichlorophenyl)-20-(4-pyridyl)porphyrin)manganese(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

manganese(II) chloride tetrahydrate + 5,10,15-tris(2,6-dichlorophenyl)-20-(4-pyridyl)porphyrin → (5,10,15-tris(2,6-dichlorophenyl)-20-(4-pyridyl)porphyrin)manganese(III) chloride (862801-25-0)

Guidance literature:

In N,N-dimethyl-formamide; refluxed; solvent removed, chromy. (alumina);

DOI:10.1016/S1381-1169(01)00200-X

Reference yield:

(5,10,15-tris(2,6-dichlorophenyl)-20-(4-pyridyl)porphyrin)manganese(III) chloride (862801-25-0) + methyl iodide (74-88-4) → (5,10,15-tris(2,6-dichlorophenyl)-20-(4-N-metylpyridyl)porphyrin)manganese(III) chloride

Guidance literature:

With Dowex 1*2-220 1-chloride; In N,N-dimethyl-formamide; an excess of CH3I at room temp.; volatiles removed (vac.), ion exchange (Dowex 1*2-200 1-chloride, 55,v/vCH3OH/dichloromethane); elem. anal.;

DOI:10.1016/S1381-1169(01)00200-X

Reference yield:

methanol (67-56-1) + silicotungstic acid hydrate + [Mn(III)Cl(5,10,15-tris(2,6-dichlorophenyl)-20-(4-pyridyl)porphyrin)] (862801-25-0) → [Mn(III)Cl(5,10,15-tris(2,6-dichlorophenyl)-20-(4-pyridyl)porphyrin)]H3[SiW12O40]*6H2O*3CH3OH

Guidance literature:

In methanol; ethanol; 1,2-dichloro-ethane; all procedures protected from light; solns. of porphyrin in C2H4Cl2:CH3OH=5:2 and H4SiW12O40 in abs. EtOH mixed with stirring; pptd., stirred overnight; ppt. sepd. by centrifugation, washed (EtOH), dried under vac.; elem. anal., detd. by DTA;

DOI:10.1016/j.molcata.2004.12.021