trans-1,4-cyclohexanediyl-4,4′-bi(1,2,4-triazole)

Base Information

• Chemical Name: trans-1,4-cyclohexanediyl-4,4′-bi(1,2,4-triazole)
• CAS No.: 1228666-86-1
• Molecular Formula: C₁₀H₁₄N₆
• Molecular Weight: 218.261
• Mol file: 1228666-86-1.mol

Synonyms:

Chemical Property of trans-1,4-cyclohexanediyl-4,4′-bi(1,2,4-triazole)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-1,4-cyclohexanediyl-4,4′-bi(1,2,4-triazole)

There total 1 articles about trans-1,4-cyclohexanediyl-4,4′-bi(1,2,4-triazole) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

trans-1,4-cyclohexyldiamine (2615-25-0) + orthoformic acid triethyl ester (122-51-0) + formic acid hydrazide (624-84-0) → trans-1,4-cyclohexanediyl-4,4′-bi(1,2,4-triazole) (1228666-86-1)

Guidance literature:

orthoformic acid triethyl ester; formic acid hydrazide; In methanol; for 2h; Reflux;

trans-1,4-cyclohexyldiamine; In methanol; for 6h; Reflux;

DOI:10.1002/ejic.201801138

Reference yield: 84.0%

trans-1,4-cyclohexanediyl-4,4′-bi(1,2,4-triazole) (1228666-86-1) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + water (7732-18-5) + silver(I) acetate (563-63-3) + vanadia → [Ag2(VO2F2)2(1,4-bis(1,2,4-triazol-4-yl)cyclohexane)]*4H2O

Guidance literature:

In water; High Pressure; placing of AgOAc, 1,4-bis(1,2,4-triazol-4-yl)cyclohexane, V2O5, H2O and aq. HF in Teflon reactor, stirring for 30 min, heating of sealed reactorat 150°C for 24 h; cooling to room temp. at rate 2-2.5°C/h, crystn. for 50 h, washing with H2O and MeOH, drying in air; elem. anal.;

DOI:10.1021/ic3000894

Reference yield: 48.0%

trans-1,4-cyclohexanediyl-4,4′-bi(1,2,4-triazole) (1228666-86-1) + molybdenum(VI) oxide → [Mo2O6(trans-1,4-cyclohexanediyl-4,4′-bi(1,2,4-triazole))]

Guidance literature:

With Co(CH₃COO)2*4H₂O; In water; High Pressure; heating soln. of molybdenum compd., cobalt compd. and triazole deriv. at180°C for 24 h; cooling to room temp. over 70 h, isolation of crystals, flotation in CHBr/CH2Cl2 mixt., elem. anal.;

DOI:10.1039/b922732f

upstream raw materials:

trans-1,4-cyclohexyldiamine

orthoformic acid triethyl ester

formic acid hydrazide