C₅H₄NC(O)NC₆H₄C(C₆H₅)NCH(CH₂CHCH₂)COONi

Base Information

Chemical Name:C₅H₄NC(O)NC₆H₄C(C₆H₅)NCH(CH₂CHCH₂)COONi
CAS No.:124303-01-1
Molecular Formula:C₂₄H₁₉N₃NiO₃
Molecular Weight:456.123
Hs Code.:

C<sub>5</sub>H<sub>4</sub>NC(O)NC<sub>6</sub>H<sub>4</sub>C(C<sub>6</sub>H<sub>5</sub>)NCH(CH<sub>2</sub>CHCH<sub>2</sub>)COONi

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₅H₄NC(O)NC₆H₄C(C₆H₅)NCH(CH₂CHCH₂)COONi

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Technology Process of C₅H₄NC(O)NC₆H₄C(C₆H₅)NCH(CH₂CHCH₂)COONi

There total 3 articles about C₅H₄NC(O)NC₆H₄C(C₆H₅)NCH(CH₂CHCH₂)COONi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 124302-98-3
(N-{phenyl[2-(pyridine-2-carboxamido)phenyl]methylidene}glycinato-N,N',N'',O)nickel(II)

: 106-95-6
allyl bromide

: 124303-01-1,353797-19-0
[Ni(NC₅H₄C(O)NC₆H₄C(C₆H₅)NCH(CH₂CHCH₂)C(O)O)]

Guidance literature:: With sodium hydroxide; tetrabutylammomium bromide; In dichloromethane; Ni complex was reacted with alkyl halide (1.1 equiv.) in presence of Bu4NBr or β-naphthol and NaOH in CH2Cl2 for 1 h;
DOI:10.1021/ja035465e

Reference yield: 75.0%

: 124302-98-3
(N-{phenyl[2-(pyridine-2-carboxamido)phenyl]methylidene}glycinato-N,N',N'',O)nickel(II)

: 556-56-9
allyl iodid

: 124303-01-1,353797-19-0
[Ni(NC₅H₄C(O)NC₆H₄C(C₆H₅)NCH(CH₂CHCH₂)C(O)O)]

Guidance literature:: With sodium hydroxide; In dichloromethane; (Ar); Ni complex was reacted with alkyl halide (1.2 equiv.) in presence of HOC10H6C10H6NH2 (0.1 equiv.) and NaOH (10-20 equiv.) in CH2Cl2 at room temp. for 4 min;
DOI:10.1021/ja035465e

Reference yield: 30.0%

: 124302-98-3
Gly-Ni-PABP

: 106-95-6
allyl bromide

: 353797-19-0,124303-01-1
C₅H₄NC(O)NC₆H₄C(C₆H₅)NCH(CH₂CHCH₂)COONi

Guidance literature:: With catalyst: N-benzylcinchonidinium chloride; KOH; In dichloromethane; phase-transfer catalysis, addn. of halide and finely ground KOH to mixt. of complex and catalyst in CH2Cl2 at -78°C, filling app. with Ar, removing cooling, agitation, ca 20°C, 1.5-2 h; decompg. by addn. of aq. MeCOOH, sepg. org. layer, extg. aq. layer with CHCl3, evapg. combined org. exts., chromy. (preparative TLC, silica gel, Me2CO-CHCl3 (1:7));
DOI:10.1007/BF00958048