trans-[RuCl2(PPh3)(κ(3)-N,N,N-2,6-bis(dihydrooxazolin-2'-yl)pyridine)]

Base Information

Chemical Name:trans-[RuCl2(PPh3)(κ(3)-N,N,N-2,6-bis(dihydrooxazolin-2'-yl)pyridine)]
CAS No.:228117-83-7
Molecular Formula:C₂₉H₂₆Cl₂N₃O₂PRu
Molecular Weight:651.494
Hs Code.:

Synonyms:

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Chemical Property of trans-[RuCl2(PPh3)(κ(3)-N,N,N-2,6-bis(dihydrooxazolin-2'-yl)pyridine)]

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Technology Process of trans-[RuCl2(PPh3)(κ(3)-N,N,N-2,6-bis(dihydrooxazolin-2'-yl)pyridine)]

There total 1 articles about trans-[RuCl2(PPh3)(κ(3)-N,N,N-2,6-bis(dihydrooxazolin-2'-yl)pyridine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 167322-64-7
trans-[RuCl2(η(2)-H2C=CH2)(κ(3)-N,N,N-2,6-bis(dihydrooxazolin-2'-yl)pyridine)]

: 603-35-0
triphenylphosphine

: 228117-83-7,236408-99-4
trans-[RuCl2(PPh3)(κ(3)-N,N,N-2,6-bis(dihydrooxazolin-2'-yl)pyridine)]

Guidance literature:: In dichloromethane; N2-atmosphere; 5 equiv. PPh3, sealed tube, 50°C, 12 h; concn., chromy. (SiO2, CH2Cl2/MeOH=100:1), solvent removal; elem. anal.;

Reference yield: 95.0%

: 14104-20-2
silver tetrafluoroborate

: 228117-83-7,236408-99-4
trans-[RuCl2(PPh3)(κ(3)-N,N,N-2,6-bis(dihydrooxazolin-2'-yl)pyridine)]

: 201230-82-2
carbon monoxide

: 1309436-72-3
[RuCl(CO)(PPh₃)(2,6-bis[oxazolin-2-yl]pyridine)]

Guidance literature:: In dichloromethane; soln. of Ru complex and AgBF4 in CH2Cl2 stirred in dark at room temp. for 1 h under CO atm.; susp. filtered, concd., mixt. of hexane/Et2O 2:1 added, solid, washed (hexane/Et2O 2:1), dried (vac.); elem. anal., XRD;
DOI:10.1016/j.jorganchem.2011.02.025

Reference yield: 77.0%

: 14104-20-2
silver tetrafluoroborate

: 228117-83-7,236408-99-4
trans-[RuCl2(PPh3)(κ(3)-N,N,N-2,6-bis(dihydrooxazolin-2'-yl)pyridine)]

: 3923-52-2
1,1-diphenyl-2-propyn-1-ol

: 228117-86-0
[RuCl(=C=C=CPh2)(PPh3)(κ(3)-N,N,N-2,6-bis(dihydrooxazolin-2'-yl)pyridine)]BF4

Guidance literature:: In dichloromethane; N2-atmosphere; stirring Ru-complex with 2 equiv. AgBF4 at room temp. in dark for 15 min, filtration, addn. of excess alkyne, stirring at room temp. for 15 min; concn., pptn. on addn. of hexane/Et2O=3:2, washing (Et2O), drying (vac.); elem. anal.;