[PtCl₂((C₆H₅)2PC₆H₄PO(OC₂H₅)2)2]

Base Information

• Chemical Name: [PtCl₂((C₆H₅)2PC₆H₄PO(OC₂H₅)2)2]
• CAS No.: 267876-51-7
• Molecular Formula: C₄₄H₄₈Cl₂O₆P₄Pt
• Molecular Weight: 1062.74
• Mol file: 267876-51-7.mol

Synonyms:

Chemical Property of [PtCl₂((C₆H₅)2PC₆H₄PO(OC₂H₅)2)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PtCl₂((C₆H₅)2PC₆H₄PO(OC₂H₅)2)2]

There total 3 articles about [PtCl₂((C₆H₅)2PC₆H₄PO(OC₂H₅)2)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + (4-diethylphosphono)phenyl-diphenylphosine (169052-23-7) → [PtCl2((C6H5)2PC6H4PO(OC2H5)2)2] (267876-51-7,442904-27-0)

Guidance literature:

In dichloromethane; under N2; stirring overnight; pptn. with Et2O; elem. anal.;

DOI:10.1039/a90S963b

Reference yield:

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + (4-diethylphosphono)phenyl-diphenylphosine (169052-23-7) → [PtCl2((C6H5)2PC6H4PO(OC2H5)2)2] (267876-51-7,442904-27-0) + PtCl2((C6H5)2PC6H4PO(OCH2CH3)2)2 (267876-51-7)

Guidance literature:

In dichloromethane; (Ar); addn. of platinum complex to a soln. of ligand in CH2Cl2, stirringat 40°C for 24 h, cooling to room temp.; filtration, evapn., crystn. (CH2Cl2/pentane), filtration, obtained as a mixt. of isomers;

DOI:10.1016/S0022-328X(02)01144-0

Reference yield:

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + (4-diethylphosphono)phenyl-diphenylphosine (169052-23-7) → [PtCl2((C6H5)2PC6H4PO(OC2H5)2)2] (267876-51-7,442904-27-0) + PtCl2((C6H5)2PC6H4PO(OCH2CH3)2)2 (267876-51-7)

Guidance literature:

In dichloromethane; (Ar); addn. of platinum complex to a soln. of ligand in CH2Cl2, stirringat 40°C for 24 h, cooling to room temp.; filtration, evapn., crystn. (CH2Cl2/pentane), filtration, obtained as a mixt. of isomers;

DOI:10.1016/S0022-328X(02)01144-0

upstream raw materials:

bis(benzonitrile)dichloroplatinum(II)

(4-diethylphosphono)phenyl-diphenylphosine

dichloro(1,5-cyclooctadiene)platinum(ll)