Fe(TPP)(⁽¹³⁾CO)(NMeIm)

Base Information

• Chemical Name: Fe(TPP)(⁽¹³⁾CO)(NMeIm)
• CAS No.: 934736-92-2
• Molecular Formula: C₄₉H₃₄FeN₆O
• Molecular Weight: 779.685
• Mol file: 934736-92-2.mol

Synonyms:

Chemical Property of Fe(TPP)(⁽¹³⁾CO)(NMeIm)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Fe(TPP)(⁽¹³⁾CO)(NMeIm)

There total 3 articles about Fe(TPP)(⁽¹³⁾CO)(NMeIm) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Fe(meso-tetraphenylporphyrin)(CO)(1-methylimidazole)] (74902-03-7) + [13C]Carbon monoxide (1641-69-6) → Fe(TPP)((13)CO)(NMeIm) (934736-92-2)

Guidance literature:

With catalyst: 10percent Pd on Al₂O₃; In n-heptane; 23°C; crystn. (CH2Cl2/pentane, ca. 5 d, gradient technique);

DOI:10.1021/ja973272j

Reference yield:

1-methyl-1H-imidazole (616-47-7) + meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) + [13C]Carbon monoxide (1641-69-6) → Fe(TPP)((13)CO)(NMeIm) (934736-92-2)

Guidance literature:

With sodium dithionite; In dichloromethane; to N-MeIm soln. Fe(III) porphyrin in CH2Cl2 was added and purged with N2for 15 min, reduced with aq. Na2S2O4, (13)CO gas was flushed for 10 min;

DOI:10.1021/ja064859d

Reference yield:

1-methyl-1H-imidazole (616-47-7) + 5,10,15,20-tetraphenyl porphyrin iron (16591-56-3) + [13C]Carbon monoxide (1641-69-6) → Fe(TPP)((13)CO)(NMeIm) (934736-92-2)

Guidance literature:

In toluene; anaerobic and dry conditions; layering with pentane, crystn. (4 days, room temp.);

DOI:10.1021/ja9740069

upstream raw materials:

1-methyl-1H-imidazole

meso-tetraphenylporphyrin iron(III) chloride

[13C]Carbon monoxide

5,10,15,20-tetraphenyl porphyrin iron