[Ga(C₅Me₄Ph)]

Base Information

• Chemical Name: [Ga(C₅Me₄Ph)]
• CAS No.: 872725-62-7
• Molecular Formula: C₁₅H₁₇*Ga
• Molecular Weight: 267.023
• Mol file: 872725-62-7.mol

Synonyms:

Chemical Property of [Ga(C₅Me₄Ph)]

Chemical Property:

Purity/Quality:

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Technology Process of [Ga(C₅Me₄Ph)]

There total 1 articles about [Ga(C₅Me₄Ph)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

gallium (7440-55-3) + 1-phenyl-2,3,4,5-tetramethylcyclopentadienylpotassium + iodine (7553-56-2,12190-71-5,8031-47-8) → [Ga(C5Me4Ph)] (872725-62-7)

Guidance literature:

In benzene; Sonication; GaI prepd. in situ from Ga and I2 in C6H6 by ultrasonic irradn., K compd. added, stirred for 48 h; filtered, washed (toluene), evapd. (vac.), distd. (vac., 125°C);

DOI:10.1021/ic051658m

Reference yield: 76.0%

[Ga(C5Me4Ph)] (872725-62-7) + [Pd3(Ga(C5Me4Ph))(μ2-Ga(C5Me4Ph))(μ3-Ga(C5Me4Ph))2(1,3-divinyl-1,1,3,3-tetramethyldisiloxane)] → [Pd2(Ga(C5Me4Ph))2(μ2-Ga(C5Me4Ph))3]

Guidance literature:

In hexane; (Ar); a suspn. of Pd complex treated with Ga(C5(CH3)4C6H5), stirred for 30 min; cooled to 0°C, sepd., washed (hexane), dried (vac.); elem. anal.;

DOI:10.1021/ic051658m

Reference yield: 72.0%

tetramethyldivinyldisiloxane (2627-95-4) + [Pd2(1,3-divinyl-1,1,3,3-tetramethyldisiloxane)3] + [Ga(C5Me4Ph)] (872725-62-7) → [Pd3(Ga(C5Me4Ph))(μ2-Ga(C5Me4Ph))(μ3-Ga(C5Me4Ph))2(1,3-divinyl-1,1,3,3-tetramethyldisiloxane)]

Guidance literature:

In hexane; (Ar); a soln. of Pd complex and ligand cooled to -30°C, treated with Ga complex, warmed slowly to room temp.; cooled to -30°C, sepd., washed (hexane), dried (vac.);

DOI:10.1021/ic051658m

upstream raw materials:

gallium

iodine