trans-[(CH₃C(O)S-4-C₆H₄C₆H₄)Pd(PPh₃)2I]

Base Information

Chemical Name:trans-[(CH₃C(O)S-4-C₆H₄C₆H₄)Pd(PPh₃)2I]
CAS No.:934273-47-9
Molecular Formula:C₅₀H₄₁IOP₂PdS
Molecular Weight:985.213
Hs Code.:

trans-[(CH<sub>3</sub>C(O)S-4-C<sub>6</sub>H<sub>4</sub>C<sub>6</sub>H<sub>4</sub>)Pd(PPh<sub>3</sub>)2I]

Synonyms:

Suppliers and Price of trans-[(CH₃C(O)S-4-C₆H₄C₆H₄)Pd(PPh₃)2I]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trans-[(CH₃C(O)S-4-C₆H₄C₆H₄)Pd(PPh₃)2I]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trans-[(CH₃C(O)S-4-C₆H₄C₆H₄)Pd(PPh₃)2I]

There total 1 articles about trans-[(CH₃C(O)S-4-C₆H₄C₆H₄)Pd(PPh₃)2I] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 933779-24-9
4-iodo-4'-thioacetylbiphenyl

: 14221-01-3
tetrakis(triphenylphosphine) palladium⁽⁰⁾

: 934273-47-9
trans-[(CH₃C(O)S-4-C₆H₄C₆H₄)Pd(PPh₃)2I]

Guidance literature:: In toluene; byproducts: PPh3; (N2); Pd complex (1 equiv.) was added to soln. of iodide in toluene at 25°C; stirred for 2 h; volatiles evapd. (vac.); dissolved in CH2Cl2; hexane added; decanted; residue washed (hexane); elem. anal.;
DOI:10.1016/j.jorganchem.2008.09.031

Reference yield: 83.0%

: 3095-81-6
1,4-bis(4-pyridylethenyl)benzene

: 934273-47-9
trans-[(CH₃C(O)S-4-C₆H₄C₆H₄)Pd(PPh₃)2I]

: 2923-28-6
silver trifluoromethanesulfonate

: trans-[((CH3C(O)S-4-C6H4C6H4)Pd(PPh3)2)(μ-C5H4NCH=CHC6H4CH=CHC5H4N)](OTf)2

Guidance literature:: In not given; Pd complex treated with Ag triflate and 0.5 equiv. of ligand;
DOI:10.1016/j.inoche.2005.10.036

Reference yield: 83.0%

: 3095-81-6
1,4-bis(4-pyridylethenyl)benzene

: 934273-47-9
trans-[(CH₃C(O)S-4-C₆H₄C₆H₄)Pd(PPh₃)2I]

: 2923-28-6
silver trifluoromethanesulfonate

: trans-[((CH3C(O)S-4-C6H4C6H4)Pd(PPh3)2)(μ-C5H4NCH=CHC6H4CH=CHC5H4N)](OTf)2*CH2Cl2

Guidance literature:: In dichloromethane; toluene; (N2); Ag salt (1 equiv.) was added to soln. of Pd complex in toluene/CH2Cl2 (5/2) at 25°C; stirred for 30 min; filtered through Celite; Nligand (0.5 equiv.) was added; stirred for 30 min; hexane added; decanted; residue dried (vac.); elem. anal.;
DOI:10.1016/j.jorganchem.2008.09.031