O¹,O³,O⁴-tribenzoyl-O²-methanesulfonyl-β-D-arabinopyranose

Base Information

• Chemical Name: O¹,O³,O⁴-tribenzoyl-O²-methanesulfonyl-β-D-arabinopyranose
• CAS No.: 122904-00-1
• Molecular Formula: C₂₇H₂₄O₁₀S
• Molecular Weight: 540.548
• Mol file: 122904-00-1.mol

Synonyms:

Chemical Property of O¹,O³,O⁴-tribenzoyl-O²-methanesulfonyl-β-D-arabinopyranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O¹,O³,O⁴-tribenzoyl-O²-methanesulfonyl-β-D-arabinopyranose

There total 6 articles about O¹,O³,O⁴-tribenzoyl-O²-methanesulfonyl-β-D-arabinopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-O-methylsulfonyl-D-glucose (61135-45-3) → O1,O3,O4-tribenzoyl-O2-methanesulfonyl-β-D-arabinopyranose (122904-00-1)

Guidance literature:

Multi-step reaction with 3 steps

1: aqueous sodium periodate

2: aqueous hydrochloric acid

3: pyridine

With pyridine; hydrogenchloride; sodium periodate;

DOI:10.1021/ja01552a056

Reference yield:

O4-formyl-O2-methanesulfonyl-D-arabinose (116009-82-6) → O1,O3,O4-tribenzoyl-O2-methanesulfonyl-β-D-arabinopyranose (122904-00-1)

Guidance literature:

Multi-step reaction with 2 steps

1: aqueous hydrochloric acid

2: pyridine

With pyridine; hydrogenchloride;

DOI:10.1021/ja01552a056

Reference yield:

(-)-benzyl 2-O-methanesulfonyl-β-D-arabinopyranoside (7143-64-8) → O1,O3,O4-tribenzoyl-O2-methanesulfonyl-β-D-arabinopyranose (122904-00-1)

Guidance literature:

Multi-step reaction with 2 steps

1: palladium; ethanol / Hydrogenation

2: pyridine

With pyridine; ethanol; palladium;

DOI:10.1021/ja01552a056

upstream raw materials:

pyridine

O²-methanesulfonyl-D-arabinose

benzoyl chloride

3-O-methylsulfonyl-D-glucose

Downstream raw materials:

methyl-(O³,O⁴-dibenzoyl-O²-methanesulfonyl-α-D-arabinopyranoside)

O¹,O³,O⁴-tribenzoyl-O²-methanesulfonyl-α-D-arabinopyranose

O³,O⁴-dibenzoyl-O²-methanesulfonyl-β-D-arabinopyranosyl bromide