Acetic acid 2-benzyloxy-1-benzyloxymethyl-ethylsulfanylmethyl ester

Base Information

• Chemical Name: Acetic acid 2-benzyloxy-1-benzyloxymethyl-ethylsulfanylmethyl ester
• CAS No.: 97151-26-3
• Molecular Formula: C₂₀H₂₄O₄S
• Molecular Weight: 360.474
• Mol file: 97151-26-3.mol

Synonyms:

Chemical Property of Acetic acid 2-benzyloxy-1-benzyloxymethyl-ethylsulfanylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Acetic acid 2-benzyloxy-1-benzyloxymethyl-ethylsulfanylmethyl ester

There total 4 articles about Acetic acid 2-benzyloxy-1-benzyloxymethyl-ethylsulfanylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dibenzyl glycerol (6972-79-8) → Acetic acid 2-benzyloxy-1-benzyloxymethyl-ethylsulfanylmethyl ester (97151-26-3)

Guidance literature:

Multi-step reaction with 4 steps

1: 96 percent / pyridine / 16 h / Ambient temperature

2: 94 percent / dimethylformamide / 2 h / 90 °C

3: 54 percent / NH₃ / methanol / 16 h / Ambient temperature

4: 1.) HCl gas / 1.) 1,2-dichloroethane, 0 deg C, 2.) DMF, RT, 2 h

With pyridine; hydrogenchloride; ammonia; In methanol; N,N-dimethyl-formamide;

DOI:10.1021/jm00147a020

Reference yield:

1,3-bis(benzyloxy)propan-2-yl 4-methylbenzene-1-sulfonate (85608-73-7) → Acetic acid 2-benzyloxy-1-benzyloxymethyl-ethylsulfanylmethyl ester (97151-26-3)

Guidance literature:

Multi-step reaction with 3 steps

1: 94 percent / dimethylformamide / 2 h / 90 °C

2: 54 percent / NH₃ / methanol / 16 h / Ambient temperature

3: 1.) HCl gas / 1.) 1,2-dichloroethane, 0 deg C, 2.) DMF, RT, 2 h

With hydrogenchloride; ammonia; In methanol; N,N-dimethyl-formamide;

DOI:10.1021/jm00147a020

Reference yield:

1-{[1,3-bis(benzyloxy)propan-2-yl]sulfanyl}ethan-1-one (97151-24-1) → Acetic acid 2-benzyloxy-1-benzyloxymethyl-ethylsulfanylmethyl ester (97151-26-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 54 percent / NH₃ / methanol / 16 h / Ambient temperature

2: 1.) HCl gas / 1.) 1,2-dichloroethane, 0 deg C, 2.) DMF, RT, 2 h

With hydrogenchloride; ammonia; In methanol;

DOI:10.1021/jm00147a020

upstream raw materials:

formaldehyd

sodium acetate

1,3-bis(benzyloxy)-2-propanethiol

dibenzyl glycerol

Downstream raw materials:

9-(acetoxymethyl)-N²-acetylguanine

N²-acetyl-7-<<1,3-bis(benzyloxy)-2-propylthio>methyl>guanine

N²-acetyl-9-<<1,3-bis(benzyloxy)-2-propylthio>methyl>guanine