(η5:η1-P-(C5H4)CH2CH2PPH2)titanium(IV)Cl3

Base Information

Chemical Name:(η5:η1-P-(C5H4)CH2CH2PPH2)titanium(IV)Cl3
CAS No.:670239-89-1
Molecular Formula:C₁₉H₁₈Cl₃PTi
Molecular Weight:431.565
Hs Code.:

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Chemical Property of (η5:η1-P-(C5H4)CH2CH2PPH2)titanium(IV)Cl3

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Technology Process of (η5:η1-P-(C5H4)CH2CH2PPH2)titanium(IV)Cl3

There total 1 articles about (η5:η1-P-(C5H4)CH2CH2PPH2)titanium(IV)Cl3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.2%

: 7550-45-0
titanium tetrachloride

: 253779-36-1
[2-(diphenylphosphanyl)ethyl]tetramethyl(trimethylsilyl)cyclopentadiene

: 670239-89-1
(η5:η1-P-(C5H4)CH2CH2PPH2)titanium(IV)Cl3

Guidance literature:: In toluene; solns. of TiCl4 and silane mixed at room temp.; left overnight; ppt. filtered of, washed (toluene), recrystd. (THF); elem. anal., detd. by NMR;
DOI:10.1016/S0277-5387(03)00407-8

Reference yield: 62.0%

: 670239-89-1
(η5:η1-C5H4CH2CH2PPh2)TiCl3

: 6921-34-2
benzylmagnesium chloride

: 908600-02-2
Ti(CH₂C₆H₅)3(C₅H₄CH₂CH₂P(C₆H₅)2)

Guidance literature:: In tetrahydrofuran; (under Ar, Schlenk); C6H5CH2MgCl in THF added dropwise to suspn. of Ti-complex in THF at -40°C, warmed slowly to 20°C, stirred for4 h; volatiles removed under reduced pressure, extd. with pentane, solvent removed under vac.; elem. anal.;
DOI:10.1021/om060370h

Reference yield: 44.0%

: 670239-89-1
(η5:η1-C5H4CH2CH2PPh2)TiCl3

: 676-58-4
methylmagnesium chloride

: 908600-23-7,908600-00-0
Ti(CH₃)2Cl(C₅H₄CH₂CH₂P(C₆H₅)2)

Guidance literature:: In tetrahydrofuran; (under Ar, Schlenk); CH3MgCl in THF added dropwise to suspn. of Ti-complex in THF at -40°C, warmed slowly to 20°C, stirred for 4 h; volatiles removed under reduced pressure, extd. with pentane, solvent removed under vac.; elem. anal.;
DOI:10.1021/om060370h