[(η6-hexamethylbenzene)RuCl2(1-(4-cyanophenyl)imidazole)]

Base Information

• Chemical Name: [(η6-hexamethylbenzene)RuCl2(1-(4-cyanophenyl)imidazole)]
• CAS No.: 832103-25-0
• Molecular Formula: C₂₂H₂₅Cl₂N₃Ru
• Molecular Weight: 503.437
• Mol file: 832103-25-0.mol

Synonyms:

Chemical Property of [(η6-hexamethylbenzene)RuCl2(1-(4-cyanophenyl)imidazole)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(η6-hexamethylbenzene)RuCl2(1-(4-cyanophenyl)imidazole)]

There total 1 articles about [(η6-hexamethylbenzene)RuCl2(1-(4-cyanophenyl)imidazole)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[RuCl2(hexamethylbenzene)]2 + 4-(1H-imidazol-1-yl)benzonitrile (25372-03-6) → [(η6-hexamethylbenzene)RuCl2(1-(4-cyanophenyl)imidazole)] (832103-25-0)

Guidance literature:

In dichloromethane; N2 atm.; a suspn. of complex in CH2Cl2 was treated with imidazole-compound, stirred at room temp. for 4 h; evapd. to dryness under reduced pressure, extd. with CH2Cl2, filtered, light petroleum was added with stirring, crystals were filtered, washed with petroleum ether, dried under vac.; elem. anal.;

DOI:10.1021/ic049256m

Reference yield: 74.0%

[2,2]bipyridinyl (366-18-7) + ammonium tetrafluroborate (13826-83-0) + [(η6-hexamethylbenzene)RuCl2(1-(4-cyanophenyl)imidazole)] (832103-25-0) → [(η6-hexamethylbenzene)Ru(1-(4-cyanophenyl)imidazole)(2,2'-bipyridine)](BF4)2

Guidance literature:

In methanol; N2 atm.; a suspn. of complex and bipyridine in methanol was heated underreflux for 1 h, cooled to room temp., filtered, NH4BF4 in methanol was added; solid was filtered out, washed with methanol and diethyl ether; elem. anal.;

DOI:10.1021/ic049256m

Reference yield: 73.5%

ammonium tetrafluroborate (13826-83-0) + [(η6-hexamethylbenzene)RuCl2(1-(4-cyanophenyl)imidazole)] (832103-25-0) + triphenylantimony (603-36-1) → [(η6-hexamethylbenzene)RuCl(1-(4-cyanophenyl)imidazole)SbPh3]BF4 (832103-43-2)

Guidance literature:

In methanol; N2 atm.; SbPh3 was added to a suspn. of complex in methanol, heated under reflux for 1 h, cooled to room temp., filtered, NH4BF4 in methanol wasadded; solid was filtered out, washed with methanol and diethyl ether; elem. anal.;

DOI:10.1021/ic049256m

upstream raw materials:

4-(1H-imidazol-1-yl)benzonitrile

Downstream raw materials:

[(η6-hexamethylbenzene)RuCl(1-(4-cyanophenyl)imidazole)PPh3]PF6

[(η6-hexamethylbenzene)RuCl(1-(4-cyanophenyl)imidazole)AsPh3]BF4

[(η6-hexamethylbenzene)RuCl(1-(4-cyanophenyl)imidazole)SbPh3]BF4

Refernces