{5-fluoro-1-(tetrahydro-2-furanyl)-2,4-(1H,3H)-pyrimidinedionato-N₃}(triphenylphosphine)gold(I)

Base Information

• Chemical Name: {5-fluoro-1-(tetrahydro-2-furanyl)-2,4-(1H,3H)-pyrimidinedionato-N₃}(triphenylphosphine)gold(I)
• CAS No.: 121860-52-4
• Molecular Formula: C₂₆H₂₃AuFN₂O₃P
• Molecular Weight: 658.419

Synonyms:

Chemical Property of {5-fluoro-1-(tetrahydro-2-furanyl)-2,4-(1H,3H)-pyrimidinedionato-N₃}(triphenylphosphine)gold(I)

Chemical Property:

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Technology Process of {5-fluoro-1-(tetrahydro-2-furanyl)-2,4-(1H,3H)-pyrimidinedionato-N₃}(triphenylphosphine)gold(I)

There total 1 articles about {5-fluoro-1-(tetrahydro-2-furanyl)-2,4-(1H,3H)-pyrimidinedionato-N₃}(triphenylphosphine)gold(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.1%

(triphenylphosphine)gold(I) chloride (14243-64-2) + tegafur (17902-23-7,65732-47-0,79107-97-4) → {5-fluoro-1-(tetrahydro-2-furanyl)-2,4-(1H,3H)-pyrimidinedionato-N3}(triphenylphosphine)gold(I) (121860-52-4)

Guidance literature:

With KOH; In tetrahydrofuran; water; under argon; gold complex, ligand and KOH were dissolved in H2O/THF; stirring at 50-60°C; precipitation by evaporation of THF; filtration; recrystallization from THF with addition of diethylether; elem.anal., IR, NMR;

DOI:10.1246/bcsj.62.1078

Reference yield:

1H-imidazole (288-32-4) + {5-fluoro-1-(tetrahydro-2-furanyl)-2,4-(1H,3H)-pyrimidinedionato-N3}(triphenylphosphine)gold(I) (121860-52-4) → 1-(triphenylphosphinegold(I))imidazole (82092-59-9)

Guidance literature:

In chloroform; the imidazole was added to a chloroform solution containing the complex; shaken vigorously for ten minutes; unreacted imidazol was extracted into the aqueous KOH phase; evaporation;

DOI:10.1246/bcsj.62.1078

Reference yield:

methylthiol (74-93-1) + {5-fluoro-1-(tetrahydro-2-furanyl)-2,4-(1H,3H)-pyrimidinedionato-N3}(triphenylphosphine)gold(I) (121860-52-4) → triphenylphosphine methanethiolate gold(I) complex (14243-52-8)

Guidance literature:

In chloroform; the thiol was added to a chloroform solution containing the complex; shaken vigorously for ten minutes; unreacted thiol was extracted into the aqueous KOH phase; evaporation;

DOI:10.1246/bcsj.62.1078

upstream raw materials:

(triphenylphosphine)gold(I) chloride

tegafur

Downstream raw materials:

1-(triphenylphosphinegold(I))imidazole

triphenylphosphine methanethiolate gold(I) complex

triphenylphosphine p-toluenethiolate gold(I) complex

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