[Ru(MeCN)((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)((1-3-η):(5,6-η)-C8H11)]BF4

Base Information

• Chemical Name: [Ru(MeCN)((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)((1-3-η):(5,6-η)-C8H11)]BF4
• CAS No.: 181139-26-4
• Molecular Formula: BF₄*C₅₄H₄₆NP₂Ru
• Molecular Weight: 958.788
• Mol file: 181139-26-4.mol

Synonyms:

Chemical Property of [Ru(MeCN)((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)((1-3-η):(5,6-η)-C8H11)]BF4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(MeCN)((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)((1-3-η):(5,6-η)-C8H11)]BF4

There total 1 articles about [Ru(MeCN)((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)((1-3-η):(5,6-η)-C8H11)]BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthalene (76189-55-4,76189-56-5,98327-87-8) + cis-[Ru(MeCN)2(cycloocta-1,5-diene)(η(3)-C3H5)]BF4 → [Ru(MeCN)((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)((1-3-η):(5,6-η)-C8H11)]BF4 (181139-26-4,180986-20-3,328381-46-0)

Guidance literature:

In acetone;

DOI:10.1021/om9603979

Reference yield: 87.0%

[Ru(MeCN)((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)((1-3-η):(5,6-η)-C8H11)]BF4 (181139-26-4,180986-20-3,328381-46-0) + methyl (Z)-2-(acetylamino)-3-phenylpropenoate (60676-51-9) → [((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)(C12H14O3N)Ru(MeCN)]BF4 (188636-51-3)

Guidance literature:

In acetone; H2-atmosphere; shaking (room temp., 10 min), cinnamate soln. addn.; evapn. (reduced pressure), CH2Cl2 addn., pptn. on Et2O addn., filtering,washing (Et2O), drying (dynamic vac., 16 h); elem. anal.;

DOI:10.1021/om980113f

Reference yield: 70.2%

[Ru(MeCN)((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)((1-3-η):(5,6-η)-C8H11)]BF4 (181139-26-4,180986-20-3,328381-46-0) + hydrogen (1333-74-0) + Dimethyl itakonate (617-52-7) → [((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthalene)Ru(MeCN)(C(CH3)(CO2CH3)(CH2CO2CH3))]BF4 (896710-23-9)

Guidance literature:

In acetone; (Ar); acetone was added to Ru complex purged with Ar in Schlenk technique; soln. was stirred for 5 min; H2 was bubbled (2 min); bubbled with Ar;itaconate was added; soln. was shaken for 5 min; solvent removed (vac.); dissolved in acetone; Et2O added; filtered; residue washed (Et2O); dried under Ar; dried in vac. overnight; elem. anal.;

DOI:10.1016/j.ica.2005.10.026

upstream raw materials:

(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthalene

Downstream raw materials:

[((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)(C₁₂H₁₄O₃N)Ru(MeCN)]BF₄

[Ru(MeCN)((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphtyl)(H)(C₄H₈O)2]BF₄

[((R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthalene)Ru(MeCN)(C(CH₃)(CO₂CH₃)(CH₂CO₂CH₃))]BF₄