2-(trimethylsilyl)-5,1'-bis(diphenylarsino)-1-(N,N-dimethylaminomethyl)ferrocene

Base Information

Chemical Name:2-(trimethylsilyl)-5,1'-bis(diphenylarsino)-1-(N,N-dimethylaminomethyl)ferrocene
CAS No.:960508-38-7
Molecular Formula:C₄₀H₄₃As₂FeNSi
Molecular Weight:771.564
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(trimethylsilyl)-5,1'-bis(diphenylarsino)-1-(N,N-dimethylaminomethyl)ferrocene

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Technology Process of 2-(trimethylsilyl)-5,1'-bis(diphenylarsino)-1-(N,N-dimethylaminomethyl)ferrocene

There total 1 articles about 2-(trimethylsilyl)-5,1'-bis(diphenylarsino)-1-(N,N-dimethylaminomethyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

: 75-77-4
chloro-trimethyl-silane

: 1271-86-9
N,N-dimethylaminomethylferrocene

: 712-48-1
chlorodiphenylarsine

: 960508-38-7
2-(trimethylsilyl)-5,1'-bis(diphenylarsino)-1-(N,N-dimethylaminomethyl)ferrocene

Guidance literature:: With n-C₄H₉Li; N,N,N',N'-tetramethylethylenediamine; In diethyl ether; (N2); using Schlenk techniques; addn. of BuLi/petr. ether to (Ph2AsC5H4)Fe(C5H2CH2NMe2SiMe3AsPh2)/Et2O; stirring for 1 h at r.t.; reflux for 15 min; addn. Me3SiCl/Et2O; stirring at 35°C for 18 h; stirring withBuLi+TMEDA (5h); addn. Ph2AsCl (24h); cooling; addn. of H2O; sepn., extn. of aq. phase with Et2O; drying of org. phase by MgSO4; evapn. of solvent; recrystn. from petroleum ether (60-90°C); elem. anal.;
DOI:10.1021/om7004468