3-butyl-1,1-dimethyl-2-phenyl-1-stannaindene

Base Information

Chemical Name:3-butyl-1,1-dimethyl-2-phenyl-1-stannaindene
CAS No.:104110-08-9
Molecular Formula:C₂₀H₂₄Sn
Molecular Weight:383.121
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-butyl-1,1-dimethyl-2-phenyl-1-stannaindene

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Technology Process of 3-butyl-1,1-dimethyl-2-phenyl-1-stannaindene

There total 5 articles about 3-butyl-1,1-dimethyl-2-phenyl-1-stannaindene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 753-73-1
dimethyltin dichloride

: 501-65-5
diphenyl acetylene

: 104110-08-9
3-butyl-1,1-dimethyl-2-phenyl-1-stannaindene

Guidance literature:: With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In hexane; benzene; byproducts: LiCl; exclusion of light, under N2; soln. of PhCCPh (hexane) added to soln. of n-BuLi (hexane) and TMEDA, stirred for 24 h at room temp., diluted with THF, warmed to reflux, transferred to soln. of Sn-compd. in warm benzene, refluxed for 30 min; filtered, washed (satd. aq. NH4Cl), dried (Na2SO4), evapd.; oil, could not be purifd. (2 impurities); 1H-NMR;

Reference yield: 45.0%

: 896728-02-2
3-butyl-1,1,2-triphenyl-1-stannaindene

: 74-88-4
methyl iodide

: 896728-04-4
3-butyl-1-methyl-1,2-diphenyl-1-stannaindene

: 104110-08-9
3-butyl-1,1-dimethyl-2-phenyl-1-stannaindene

Guidance literature:: With Li; In diethyl ether; byproducts: C6H5Li; (Ar); ether was added to mixt. of Sn compd. and Li (2.5 equiv.) at room temp.; stirred for 4 h; MeI was added; filtered; volatiles removed; chromd. (gel permeation); elem. anal.;
DOI:10.1021/om050879x

Reference yield: 40.0%

: 896728-02-2
3-butyl-1,1,2-triphenyl-1-stannaindene

: 74-88-4
methyl iodide

: 104110-08-9
3-butyl-1,1-dimethyl-2-phenyl-1-stannaindene

Guidance literature:: With Li; In diethyl ether; byproducts: C6H5Li; (Ar); ether was added to mixt. of Sn compd. and Li at room temp.; stirred for 3 h; refluxed for 14 h; MeI was added; volatiles removed; chromd. (gel permeation);
DOI:10.1021/om050879x