(5,10,15,20-tetra-p-tolylporphyrinato)2-ethylrhodium(III)

Base Information

Chemical Name:(5,10,15,20-tetra-p-tolylporphyrinato)2-ethylrhodium(III)
CAS No.:441353-09-9
Molecular Formula:C₅₀H₄₁N₄Rh
Molecular Weight:800.808
Hs Code.:

Synonyms:

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Chemical Property of (5,10,15,20-tetra-p-tolylporphyrinato)2-ethylrhodium(III)

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Technology Process of (5,10,15,20-tetra-p-tolylporphyrinato)2-ethylrhodium(III)

There total 4 articles about (5,10,15,20-tetra-p-tolylporphyrinato)2-ethylrhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 74-96-4
ethyl bromide

: 205259-72-9
rhodium(III) tetrakis(4-tolyl)porphyrin chloride

: 441353-09-9
(5,10,15,20-tetra-p-tolylporphyrinato)2-ethylrhodium(III)

Guidance literature:: With sodium hydroxide; sodium tetrahydroborate; In ethanol; water; under N2 atm. to suspn. Rh complex in EtOH soln. NaBH4 in aq. 0.1 M NaOHwas added and heated at 50°C for 1 h, soln. was cooled to 30.deg ree.C, EtBr was added and stirred at room temp. for 15 min; react. mixt. was worked up by extraction with CH2Cl2/H2O, org. phase wasdried over MgSO4, filtered and evapd., residue was purified by column c hromy. on silica (hexane-CH2Cl2 4:1); elem. anal.;
DOI:10.1016/j.jorganchem.2007.11.009

Reference yield: 37.0%

: 205259-72-9
rhodium(III) tetrakis(4-tolyl)porphyrin chloride

: 64-17-5
ethanol

: 441353-09-9
(5,10,15,20-tetra-p-tolylporphyrinato)2-ethylrhodium(III)

Guidance literature:: With potassium carbonate; In benzonitrile; at 120 ℃; for 24h; Inert atmosphere;
DOI:10.1021/acs.organomet.9b00454

Reference yield: 17.0%

: 205259-72-9
rhodium(III) tetrakis(4-tolyl)porphyrin chloride

: 121-44-8
triethylamine

: 441353-09-9
(5,10,15,20-tetra-p-tolylporphyrinato)2-ethylrhodium(III)

Guidance literature:: In triethylamine; mixt. of Rh complex (0.014 mmol) and Et3N degassed (3 freeze-pump-thaw cycles), heated under N2 at 120°C for 1 d; solvent evapd. in vac., residue chromd. (silica gel, hexane/CH2Cl2 eluent (1:1));
DOI:10.1016/j.jorganchem.2010.02.007