cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2]Pd(chloride)2*(dichloromethane)

Base Information

• Chemical Name: cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2]Pd(chloride)2*(dichloromethane)
• CAS No.: 1312549-08-8
• Molecular Formula: CH₂Cl₂*C₂₈H₂₂Cl₂N₆P₂PdPtS₂
• Molecular Weight: 1025.94
• Mol file: 1312549-08-8.mol

Synonyms:

Chemical Property of cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2]Pd(chloride)2*(dichloromethane)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2]Pd(chloride)2*(dichloromethane)

There total 2 articles about cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2]Pd(chloride)2*(dichloromethane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + dichloromethane (75-09-2) + cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2] (1033762-75-2,1033629-97-8) → cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2]Pd(chloride)2*(dichloromethane) (1312549-08-8)

Guidance literature:

In dichloromethane; toluene; byproducts: C6H5CN; (Ar), Schlenk techniques; addn. of Pd to soln. of Pt complex in CH2Cl2/toluene, stirring under reflux for 3 h; cooling to room temp., evapn. under reduced pressure, washing with CH2Cl2, evapn. under reduced pressure, elem. anal.;

DOI:10.1039/c0dt01782e

Reference yield:

cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2][Au(chloride)]2 → cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2]Pd(chloride)2*(dichloromethane) (1312549-08-8)

Guidance literature:

Multi-step reaction with 2 steps

1: not given

2: dichloromethane; toluene

In dichloromethane; toluene;

DOI:10.1039/c0dt01782e

Reference yield: 73.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2]Pd(chloride)2*(dichloromethane) (1312549-08-8) → cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2]Pd(chloride)2(BF4)2

Guidance literature:

In dichloromethane; (Ar), Schlenk techniques; addn. of soln. of B compd. to soln. of P compd. in CH2Cl2, storage for 10 min; evapn. under reduced pressure, washing with Et2O, dissolving in MeCN, layering with Et2O, elem. anal.;

DOI:10.1039/c0dt01782e

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

dichloromethane

cis-[Pt((N-(diphenylphosphino)-1,3,4-thiadiazol-2-amine)(-1H))2]