2-Propenoic acid, 2,2'-[oxybis(methylene)]bis-, dimethyl ester

Base Information

• Chemical Name: 2-Propenoic acid, 2,2'-[oxybis(methylene)]bis-, dimethyl ester
• CAS No.: 109669-53-6
• Molecular Formula: C10H14O5
• Molecular Weight: 214.218
• DSSTox Substance ID: DTXSID20448440
• Nikkaji Number: J2.139.967A
• Mol file: 109669-53-6.mol

Synonyms:109669-53-6;2-Propenoic acid, 2,2'-[oxybis(methylene)]bis-, dimethyl ester;Methyl 2-(2-methoxycarbonylprop-2-enoxymethyl)prop-2-enoate;SCHEMBL353002;DTXSID20448440;VOTNBIJNPNEGJA-UHFFFAOYSA-N;4,4'-Oxybis(methacrylic acid methyl) ester;Methyl 4-oxahept-1,6-diene-2,6-dicarboxylate;dimethyl 2,2'-[oxybis(methylene)]bis-2-propenoate

Chemical Property of 2-Propenoic acid, 2,2'-[oxybis(methylene)]bis-, dimethyl ester

Chemical Property:

• XLogP3: 0.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 8
• Exact Mass: 214.08412354
• Heavy Atom Count: 15
• Complexity: 252

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)C(=C)COCC(=C)C(=O)OC

Technology Process of 2-Propenoic acid, 2,2'-[oxybis(methylene)]bis-, dimethyl ester

There total 5 articles about 2-Propenoic acid, 2,2'-[oxybis(methylene)]bis-, dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → methyl 2-hydroxymethylacrylate (15484-46-5) + dimethyl 2,2′-[oxybis(methylene)]diacrylate (109669-53-6)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; at 95 ℃; for 4h;

Reference yield: 13.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + ethyl acrylate (140-88-5,9003-32-1) → methyl 2-hydroxymethylacrylate (15484-46-5) + dimethyl 2,2′-[oxybis(methylene)]diacrylate (109669-53-6)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; for 19h; Heating;

DOI:10.1016/S0040-4020(97)00968-X

Reference yield:

methanol (67-56-1) + 2-(2-chlorocarbonyl-allyloxymethyl)-acryloylchloride (652966-97-7) → dimethyl 2,2′-[oxybis(methylene)]diacrylate (109669-53-6)

Guidance literature:

at 45 ℃; for 12h;

DOI:10.1021/ma501232n

upstream raw materials:

methyl 2-hydroxymethylacrylate

formaldehyd

acrylic acid methyl ester

ethyl acrylate

Downstream raw materials:

methyl 2-(bromomethyl)propenoate