tert-Butyl(dimethyl){[4-(trimethylsilyl)but-3-yn-1-yl]oxy}silane

Base Information

Chemical Name:tert-Butyl(dimethyl){[4-(trimethylsilyl)but-3-yn-1-yl]oxy}silane
CAS No.:110519-15-8
Molecular Formula:C13H28OSi2
Molecular Weight:256.536
Hs Code.:
DSSTox Substance ID:DTXSID60546535
Nikkaji Number:J832.813G
Wikidata:Q82424400
Mol file:110519-15-8.mol

Synonyms:110519-15-8;SCHEMBL789464;DTXSID60546535;PJCKHWHRIGMRBO-UHFFFAOYSA-N;tert-Butyl(dimethyl){[4-(trimethylsilyl)but-3-yn-1-yl]oxy}silane;1-(Trimethylsilyl)-4-(t-butyldimethylsiloxy)-1-butyne

Suppliers and Price of tert-Butyl(dimethyl){[4-(trimethylsilyl)but-3-yn-1-yl]oxy}silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-Butyl(dimethyl){[4-(trimethylsilyl)but-3-yn-1-yl]oxy}silane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:5
Exact Mass:256.16786858
Heavy Atom Count:16
Complexity:281

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OCCC#C[Si](C)(C)C

Technology Process of tert-Butyl(dimethyl){[4-(trimethylsilyl)but-3-yn-1-yl]oxy}silane

There total 1 articles about tert-Butyl(dimethyl){[4-(trimethylsilyl)but-3-yn-1-yl]oxy}silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 288-32-4
1H-imidazole

: 18162-48-6
tert-butyldimethylsilyl chloride

: 927-74-2
3-Butyn-1-ol

: 78592-82-2
4-(tert-butyldimethylsilyloxy)-1-butyne

: 110519-15-8
tert-butyldimethyl{[4-(trimethylsilyl)but-3-yn-1-yl]oxy}silane

Guidance literature:: In N,N-dimethyl-formamide;

Reference yield: 55.0%

: 1357115-31-1
2-benzyl-9-((4-methoxybenzyl)oxy)non-1-en-6-yn-4-ol

: 110519-15-8
tert-butyldimethyl{[4-(trimethylsilyl)but-3-yn-1-yl]oxy}silane

: C₃₇H₅₆O₄Si₂

: 3a-benzyl-6-(2-((tert-butyldimethylsilyl)oxy)ethyl)-7-(2-((4-methoxybenzyl)oxy)ethyl)-5-(trimethylsilyl)-2,3,3a,4-tetrahydro-1H-inden-2-ol

Guidance literature:: tert-butyldimethyl{[4-(trimethylsilyl)but-3-yn-1-yl]oxy}silane; With titanium(IV)isopropoxide; cyclopentylmagnesium chloride; In diethyl ether; toluene; at -78 - -30 ℃; Inert atmosphere;

2-benzyl-9-((4-methoxybenzyl)oxy)non-1-en-6-yn-4-ol; With n-butyllithium; In diethyl ether; hexane; toluene; at -78 - 23 ℃; for 16h; optical yield given as %de; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ja2105043