Triethyliodosilane

Base Information

• Chemical Name: Triethyliodosilane
• CAS No.: 1112-49-8
• Molecular Formula: C6H15ISi
• Molecular Weight: 242.175
• DSSTox Substance ID: DTXSID20455871
• Nikkaji Number: J812.558I
• Wikidata: Q63398701
• Mol file: 1112-49-8.mol

Synonyms:triethyliodosilane;1112-49-8;TRIETHYL(IODO)SILANE;Silane, triethyliodo-;iodotriethylsilane;SCHEMBL329618;DTXSID20455871;Q63398701

Chemical Property of Triethyliodosilane

Chemical Property:

• Boiling Point: 190.5 °C(Press: 744 Torr)
• PSA: 0.00000
• Density: 1.4 g/cm3
• LogP: 3.42660
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 241.99877
• Heavy Atom Count: 8
• Complexity: 51.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triethyliodosilane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Si](CC)(CC)I

Technology Process of Triethyliodosilane

There total 26 articles about Triethyliodosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

triethylsilyl phenylselenide (76358-43-5) → triethylsilyl iodide (1112-49-8) + diphenyl diselenide (1666-13-3)

Guidance literature:

With iodine;

DOI:10.1021/jo00320a012

Reference yield: 90.0%

butyryl iodide (78209-72-0) → triethylsilyl iodide (1112-49-8) + butyl butyrate (109-21-7)

Guidance literature:

With triethylsilane; bis(acetylacetonate)nickel(II); at 20 ℃; for 2h;

Reference yield: 86.0%

hexaethyldisilane (1633-09-6) → triethylsilyl iodide (1112-49-8)

Guidance literature:

With I₂; In tetrachloromethane;

DOI:10.1021/jo50018a019

upstream raw materials:

triethylsilane

triethylsilane

triethylsilyl fluoride

hexaethyl disiloxane

Downstream raw materials:

hexaethyldisilane

hexaethyl disiloxane

triethylsilylphenylethyne

iodine

Refernces

• 1、 Lister,Marson. "". . p. 2101,2103. Retrieved 1964.
• 2、 Voronkov,Trukhina,Belousova,Tsyrendorzhieva,Vlasova. "Acyl iodides in organic synthesis: X. Reactions with triorganylsilanes and triphenylgermane". experimental part. p. 1751 - 1753. Retrieved 2009/09/29.
• 3、 Voronkov,Trukhina,Belousova,Kuznetsova,Vlasova. "Acyl iodides in organic synthesis: IX. Cleavage of the Si-O-C and Si-O-Si moieties". . p. 501 - 506. Retrieved 2008/02/02.