Triethylfluorosilane

Base Information

• Chemical Name: Triethylfluorosilane
• CAS No.: 358-43-0
• Molecular Formula: C6H15 F Si
• Molecular Weight: 134.269
• Hs Code.: 2931900090
• European Community (EC) Number: 206-617-3
• UNII: W38ZR5CD7Y
• DSSTox Substance ID: DTXSID40189328
• Nikkaji Number: J193.856H
• Wikidata: Q83061378
• Mol file: 358-43-0.mol

Synonyms:TRIETHYLFLUOROSILANE;358-43-0;Fluorotriethylsilane;triethyl(fluoro)silane;Silane, triethylfluoro-;C6H15FSi;EINECS 206-617-3;MFCD00053170;Triethylsilyl fluoride;triethyl-fluoro-silane;W38ZR5CD7Y;SCHEMBL707900;C6-H15-F-Si;DTXSID40189328;AKOS006272093;CS-O-11804;AS-32437;SY026855;FT-0728321;A913623

Chemical Property of Triethylfluorosilane

Chemical Property:

• Vapor Pressure: 31mmHg at 25°C
• Refractive Index: 1.3900
• Boiling Point: 107.9°Cat760mmHg
• Flash Point: 19°C
• PSA: 0.00000
• Density: 0.795g/cm³
• LogP: 2.96110
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 134.09270517
• Heavy Atom Count: 8
• Complexity: 51.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triethylfluorosilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Si](CC)(CC)F

Technology Process of Triethylfluorosilane

There total 83 articles about Triethylfluorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

triethyl(1-phenylethoxy)silane (112473-30-0,18442-52-9) → triethylsilyl fluoride (358-43-0) + 1-Phenylethanol (98-85-1,13323-81-4)

Guidance literature:

With methylammmonium fluoride; In methanol; at 20 ℃; for 24h;

Reference yield: 100.0%

ethyl α-triethylsiloxypropionate (109170-82-3,117382-34-0) → ethyl 2-hydroxypropionate (97-64-3,2676-33-7) + triethylsilyl fluoride (358-43-0)

Guidance literature:

With methylammmonium fluoride; In methanol; at 20 ℃; for 24h; further solvents (CH₃CN/THF, THF, dioxane), other temperature;

Reference yield: 85.0%

potassium fluoride (7789-23-3) + triethylsilyl formate (18296-01-0) → triethylsilyl fluoride (358-43-0) + potassium formate (590-29-4)

Guidance literature:

at 20 ℃; for 0.25h; Schlenk technique; Inert atmosphere; Glovebox;

DOI:10.1021/om400876j

upstream raw materials:

triethylsilylamine

Triethylsilanol

triethylsilyl chloride

triethyl-bromo-silane

Downstream raw materials:

triethyl-methyl-silane

triethylsilane

Triethylsilanol

triethylsilyl iodide

Refernces

• 1、 Petrov et al.. "". . . Retrieved 1973.
• 2、 Gierut,Sowa,Nieuwland. "-". . p. 897,898. Retrieved 1936.
• 3、 Wozniak, Martin,Braun, Thomas,Ahrens, Mike,Braun-Cula, Beatrice,Wittwer, Philipp,Herrmann, Roy,Laubenstein, Reik. "Activation of SF6 at a Xantphos-Type Rhodium Complex". . p. 821 - 828. Retrieved 2018.
• 4、 Watanabe et al.. "-". . p. 1461,1463. Retrieved 1965.
• 5、 Greb, Lutz,Hanusch, Franziska,Inoue, Shigeyoshi,Thorwart, Thadd?us,Tschernuth, Florian S.. "Bis(perfluoropinacolato)silane: A Neutral Silane Lewis Superacid Activates Si?F Bonds". supporting information. p. 25799 - 25803. Retrieved 2021/11/09.
• 6、 Hermannsdorfer, André,Driess, Matthias. "Isolable Silicon-Based Polycations with Lewis Superacidity". supporting information. p. 23132 - 23136. Retrieved 2020/10/19.