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1112-49-8

Basic Information
CAS No.: 1112-49-8
Name: triethyliodosilane
Article Data: 30
Molecular Structure:
Molecular Structure of 1112-49-8 (triethyliodosilane)
Formula: C6H15ISi
Molecular Weight: 242.175
Synonyms: iodotriethylsilane;Triaethyl-jod-silan;triethyl-iodosilane;Silane,triethyliodo;(+)-triethylsilyl iodide;
Density: 1.4 g/cm3
Boiling Point: 190.5 °C(Press: 744 Torr)
PSA: 0.00000
LogP: 3.42660
Synthetic route
76358-43-5

triethylsilyl phenylselenide

A

1112-49-8

triethylsilyl iodide

B

1666-13-3

diphenyl diselenide

Conditions
ConditionsYield
With iodineA 89%
B 96%
617-86-7

triethylsilane

A

1112-49-8

triethylsilyl iodide

B

109-21-7

butyl butyrate

Conditions
ConditionsYield
With butyryl iodide; bis(acetylacetonate)nickel(II) at 20℃; for 2h;A 90%
B 81%
78209-72-0

butyryl iodide

A

1112-49-8

triethylsilyl iodide

B

109-21-7

butyl butyrate

Conditions
ConditionsYield
With triethylsilane; bis(acetylacetonate)nickel(II) at 20℃; for 2h;A 90%
B 81%
1633-09-6

hexaethyldisilane

1112-49-8

triethylsilyl iodide

Conditions
ConditionsYield
With I2 In tetrachloromethane86%
With I2 In tetrachloromethane86%
617-86-7

triethylsilane

1112-49-8

triethylsilyl iodide

Conditions
ConditionsYield
With methyl iodide; palladium dichloride at 20℃; for 1.5h;85%
With I285%
With acetyl iodide In toluene at 100℃; for 6h;58%
617-86-7

triethylsilane

75-52-5

nitromethane

16029-98-4

trimethylsilyl iodide

A

1112-49-8

triethylsilyl iodide

B

107-46-0

Hexamethyldisiloxane

C

2652-41-7

1,1,1-triethyl-3,3,3-trimethyl-disiloxane

D

994-49-0

hexaethyl disiloxane

E

14965-49-2

methylamine hydroiodide

Conditions
ConditionsYield
Product distribution; Mechanism; 2 h at -5 deg C, then 5 h at 30 deg C;A n/a
B n/a
C n/a
D n/a
E 80%
994-49-0

hexaethyl disiloxane

7784-23-8

aluminium(III) iodide

1112-49-8

triethylsilyl iodide

Conditions
ConditionsYield
80%
358-43-0

triethylsilyl fluoride

1112-49-8

triethylsilyl iodide

Conditions
ConditionsYield
With I2; Al75%
With I2; AlI359%
With aluminium(III) iodide
With iodine; aluminium
994-30-9

triethylsilyl chloride

1112-49-8

triethylsilyl iodide

Conditions
ConditionsYield
With lithium iodide at 50℃; for 4h;65%
Multi-step reaction with 2 steps
1: 1.) Na / 1.) THF, 3 h, reflux, 2.) 16 h, reflux
2: 89 percent / I2
View Scheme
With sodium iodide In DMF (N,N-dimethyl-formamide); acetonitrile at 20℃; for 1h; Product distribution / selectivity;
542-91-6

H2SiEt2

75-03-6

ethyl iodide

A

1112-49-8

triethylsilyl iodide

B

18243-16-8

diethyldiiodosilane

Conditions
ConditionsYield
palladium dichloride at 60℃; for 12h;A 36%
B 31%
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