monomethoxy(methyl)phenylsilane

Base Information

• Chemical Name: monomethoxy(methyl)phenylsilane
• CAS No.: 147377-22-8
• Molecular Formula: C₈H₁₂OSi
• Molecular Weight: 152.268
• Mol file: 147377-22-8.mol

Synonyms:

Chemical Property of monomethoxy(methyl)phenylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of monomethoxy(methyl)phenylsilane

There total 13 articles about monomethoxy(methyl)phenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

methanol (67-56-1) + methylphenylsilane (766-08-5,146088-00-8) → monomethoxy(methyl)phenylsilane (32545-54-3,147377-22-8,147377-33-1)

Guidance literature:

With iron(II)β-diketiminate complex; In benzene-d6; at 20 ℃; for 18h;

DOI:10.1021/acscatal.0c01440

Reference yield: 5.0%

dimethoxy(methyl)phenylsilane (3027-21-2) → monomethoxy(methyl)phenylsilane (32545-54-3,147377-22-8,147377-33-1) + methylphenylsilane (766-08-5,146088-00-8)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; ethyl bromide; tetraoctyl ammonium bromide; In benzene-d6; at 20 ℃; for 24h;

DOI:10.1039/c9cc01961h

Reference yield:

dimethoxy(methyl)phenylsilane (3027-21-2) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → monomethoxy(methyl)phenylsilane (32545-54-3,147377-22-8,147377-33-1) + methylphenylsilane (766-08-5,146088-00-8)

Guidance literature:

With (η⁵-C₅Me₄SiMe₃)₂YH(thf); In benzene-d6; at 100 ℃; for 24h; Inert atmosphere;

DOI:10.1021/acs.organomet.8b00798

upstream raw materials:

methanol

2-phenylheptamethyltrisilane

chloro(methyl)phenylsilane

trimethyl orthoformate