1'-(diphenylphosphino)-1-[(pyrid-2-yl)hydroxymethyl]ferrocene

Base Information

Chemical Name:1'-(diphenylphosphino)-1-[(pyrid-2-yl)hydroxymethyl]ferrocene
CAS No.:1235551-29-7
Molecular Formula:C₂₈H₂₄FeNOP
Molecular Weight:477.325
Hs Code.:

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Chemical Property of 1'-(diphenylphosphino)-1-[(pyrid-2-yl)hydroxymethyl]ferrocene

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Technology Process of 1'-(diphenylphosphino)-1-[(pyrid-2-yl)hydroxymethyl]ferrocene

There total 1 articles about 1'-(diphenylphosphino)-1-[(pyrid-2-yl)hydroxymethyl]ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 1121-60-4
pyridine-2-carbaldehyde

: 185223-97-6
1′-(diphenylphosphino)-1-bromoferrocene

: 12098-17-8
(diphenylphosphin)ferrocene

: 1235551-29-7
1'-(diphenylphosphino)-1-[(pyrid-2-yl)hydroxymethyl]ferrocene

: 1235551-40-2
[Ph₂P(ferrocene-1,1'-diyl)C(O)(2-pyridyl)]

Guidance literature:: With BuLi; In tetrahydrofuran; hexane; (Ar); exclusion of light; soln. of Fe complex in THF was treated with BuLi/hexane with stirring at -78°C; after 15 min aldehyde was added; stirred at -78°C for 15 min and at room temp. for 90 min; H2O added; stirred for 30 min; extd. (CH2Cl2); washed (satd. aq. NaHCO3,satd. aq. NaCl); dried (MgSO4); evapd. (vac.); chromd. (silica gel, EtO Ac/hexane, 1/5, 1/1); evapd.; elem. anal.;
DOI:10.1021/om100339p

Reference yield: 55.0%

: 1235551-29-7
1'-(diphenylphosphino)-1-[(pyrid-2-yl)hydroxymethyl]ferrocene

: 1235551-28-6
1'-(diphenylphosphino)-1-[(pyrid-2-yl)methyl]ferrocene

Guidance literature:: With SmI₂; (Me₂N)3PO; pivalic acid; In tetrahydrofuran; (Ar); exclusion of light; soln. of SmI2 in THF was added to stirred mixt. of Fe complex and (Me2N)3PO in THF over 10 min; stirred for 5 min; soln. of acid in THF was added; stirred for 15 min; dild. with ether, satd. aq. NaCl; org. phase septd.; aq. layer extd. (Et2O/C6H14); combined org. phase washed (satd. aq. NaCl); dried (MgSO4); evapd.; chromd. (silica gel, EtOAc/C6H14, 1/1); evapd.; chromd. (alumina,Et2O/C6H14, 4/1); evapd; dried (vac.;
DOI:10.1021/om100339p