IrOs(H)2(CO)3((C₆H₄)C₆H₅PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂P(C₆H₅)2)

Base Information

• Chemical Name: IrOs(H)2(CO)3((C₆H₄)C₆H₅PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂P(C₆H₅)2)
• CAS No.: 132959-03-6
• Molecular Formula: C₅₃H₄₅IrO₃OsP₄
• Molecular Weight: 1236.25
• Mol file: 132959-03-6.mol

Synonyms:

Chemical Property of IrOs(H)2(CO)3((C₆H₄)C₆H₅PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂P(C₆H₅)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrOs(H)2(CO)3((C₆H₄)C₆H₅PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂P(C₆H₅)2)

There total 2 articles about IrOs(H)2(CO)3((C₆H₄)C₆H₅PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂P(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

IrOs(H)2(CO)3((C6H5)2PCH2P(C6H5)2)2(1+)*BF4(1-) = {IrOs(H)2(CO)3(((C6H5)2P)2CH2)2}BF4 (132939-86-7) + sodium hydride (7646-69-7) → IrOs(H)2(CO)3((C6H4)C6H5PCH2P(C6H5)2)((C6H5)2PCH2P(C6H5)2) (132959-03-6)

Guidance literature:

In tetrahydrofuran; (Ar); added THF to NaH and Ir-complex; stirred vigorously for 1 h; evapd. (vac.); (31)P NMR, IR;

DOI:10.1021/om00051a018

Reference yield: 75.0%

{N(P(C6H5)3)2}(1+)*{HOs(CO)4}(1-)={N(P(C6H5)3)2}{HOs(CO)4} (79408-53-0) + [IrCl(bis(diphenylphosphino)methane)2] (132939-91-4) → IrOs(H)2(CO)3((C6H4)C6H5PCH2P(C6H5)2)((C6H5)2PCH2P(C6H5)2) (132959-03-6)

Guidance literature:

In tetrahydrofuran; (Ar); added a soln. of Os-compound to stirred soln. of Ir-complex; stirred at room temp. for 16 h; concentrated; added diethyl ether; pptd.; evapd.; recrystd. from THF/hexane; elem. anal.;

DOI:10.1021/om00051a018

Reference yield: 79.0%

silver tetrafluoroborate (14104-20-2) + (triphenylphosphine)gold(I) chloride (14243-64-2) + IrOs(H)2(CO)3((C6H4)C6H5PCH2P(C6H5)2)((C6H5)2PCH2P(C6H5)2) (132959-03-6) → IrOs(H)(AuP(C6H5)3)(CO)3((C6H5)2PCH2P(C6H5)2)2(1+)*BF4(1-) = {IrOs(H)(AuP(C6H5)3)(CO)3(((C6H5)2P)2CH2)2}BF4 (132939-88-9)

Guidance literature:

In tetrahydrofuran; acetone; byproducts: AgCl; (Ar); added a soln. of Au-compound in acetone to AgBF4; stirred for 1 h; filtered; evapd.; dissolved in THF; added to stirred soln. of Ir-complex; stirred for 1 h; filtered; evapd.; recrystd. from CH2Cl2/Et2O at room temp.; elem. anal.;

DOI:10.1021/om00051a018

upstream raw materials:

IrOs(H)2(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)2(CO)3(((C₆H₅)2P)2CH₂)2}BF₄

sodium hydride

{N(P(C₆H₅)3)2}⁽¹⁺⁾*{HOs(CO)4}^(1-)={N(P(C₆H₅)3)2}{HOs(CO)4}

[IrCl(bis(diphenylphosphino)methane)2]

Downstream raw materials:

IrOs(H)(AuP(C₆H₅)3)(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)(AuP(C₆H₅)3)(CO)3(((C₆H₅)2P)2CH₂)2}BF₄

IrOs(H)2(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)2(CO)3(((C₆H₅)2P)2CH₂)2}BF₄

Refernces