2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dithiadigermetane

Base Information

• Chemical Name: 2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dithiadigermetane
• CAS No.: 114552-14-6
• Molecular Formula: C36H44Ge2S2
• Molecular Weight: 686.057
• DSSTox Substance ID: DTXSID60587226
• Wikidata: Q82479595

Synonyms:114552-14-6;2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dithiadigermetane;DTXSID60587226

Chemical Property of 2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dithiadigermetane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 686.1316973
• Heavy Atom Count: 40
• Complexity: 687

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=CC(=C(C(=C1)C)[Ge]2(S[Ge](S2)(C3=C(C=C(C=C3C)C)C)C4=C(C=C(C=C4C)C)C)C5=C(C=C(C=C5C)C)C)C

Technology Process of 2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dithiadigermetane

There total 10 articles about 2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dithiadigermetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

dichlorodimesitylgermane (96481-42-4) + thiourea (17356-08-0) → 2,2,4,4-tetramesityl-1,3,2,4-dithiadigermetane (114552-14-6) + tetramesitylcyclodigermazane (137195-86-9) + ((CH3)3C6H2)2GeNHGe((CH3)3C6H2)2S (137196-33-9)

Guidance literature:

With triethylamine; In tetrahydrofuran; byproducts: hydrochloric acid;

DOI:10.1016/S0020-1693(00)81668-0

Reference yield: 46.0%

sulfur (10544-50-0) + 2,2,3,3-tetramesitylthiadigermirane (107824-86-2) → 2,2,4,4-tetramesityl-1,3,2,4-dithiadigermetane (114552-14-6)

Guidance literature:

In toluene; reflux, 20 h; preparative TLC (silica gel, benzene/hexane);

DOI:10.1021/om00099a018

Reference yield: 42.0%

2,2,3,3-tetramesitylthiadigermirane (107824-86-2) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → 1,1-bis(2,4,6-trimethylphenyl)-3,4-dimethylgermacyclopent-3-ene (83686-73-1) + 2,2,4,4-tetramesityl-1,3,2,4-dithiadigermetane (114552-14-6)

Guidance literature:

In cyclohexane; Irradiation (UV/VIS); irradiation with a low-pressure mercury lamp for 5 h at room temp.; preparative TLC (silica gel, benzene/hexane); spectral data are identical with those of authentic samples;

DOI:10.1021/om00099a018

upstream raw materials:

sulfur

hexamesitylcyclotrigermane

((CH₃)3C₆H₂)2GeP(C₆H₂(C(CH₃)3)3)S

2,2,3,3-tetramesitylthiadigermirane

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