tetrahydridotris(triphenylphosphine)ruthenium(IV)

Base Information

• Chemical Name: tetrahydridotris(triphenylphosphine)ruthenium(IV)
• CAS No.: 31275-06-6
• Molecular Formula: C₅₄H₄₉P₃Ru
• Molecular Weight: 891.974
• Mol file: 31275-06-6.mol

Synonyms:

Chemical Property of tetrahydridotris(triphenylphosphine)ruthenium(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetrahydridotris(triphenylphosphine)ruthenium(IV)

There total 11 articles about tetrahydridotris(triphenylphosphine)ruthenium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

sodium tetrahydroborate (16940-66-2) + tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) → tetrahydridotris(triphenylphosphine)ruthenium(IV) (31275-06-6,1227617-46-0)

Guidance literature:

In ethanol; addn. of 4 equiv. NaBH4 to Ru-complex soln. (room temp., pptn.); filtration, washing (MeOH, H2O, MeOH), drying (vac.); elem. anal.;

DOI:10.1039/DT9780000885

Reference yield: 80.0%

mer-RuH(OCPhC6H4)(PPh3)3 → tetrahydridotris(triphenylphosphine)ruthenium(IV) (31275-06-6,1227617-46-0)

Guidance literature:

With hydrogen; In tetrahydrofuran-d8; byproducts: Ph2CHOH; 25°C; < 5min; reaction of equilibrium;;

DOI:10.1016/0022-328X(87)80284-X

Reference yield: 70.0%

dihydrido(tetrahydrofuran)tris(triphenylphosphine)ruthenium(II) (65296-42-6) → tetrahydridotris(triphenylphosphine)ruthenium(IV) (31275-06-6,1227617-46-0)

Guidance literature:

With hydrogen; In tetrahydrofuran-d8; 25°C; < 5min;;

DOI:10.1016/0022-328X(87)80284-X

upstream raw materials:

sodium tetrahydroborate

tris(triphenylphosphine)ruthenium(II) chloride

{Ru(hydrogen)2(nitrogen)(triphenylphosphine)3}

dihydrido(tetrahydrofuran)tris(triphenylphosphine)ruthenium(II)

Downstream raw materials:

1,1-Diphenylmethanol

cis-[RuH₂((dimethylamino)difluorophosphine)2(triphenylphosphine)2]

cis-[RuH₂(trifluorophosphine)2(triphenylphosphine)2]

cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)ruthenium(II)