dihydrido(tetrahydrofuran)tris(triphenylphosphine)ruthenium(II)

Base Information

• Chemical Name: dihydrido(tetrahydrofuran)tris(triphenylphosphine)ruthenium(II)
• CAS No.: 65296-42-6
• Molecular Formula: C₅₈H₅₅OP₃Ru
• Molecular Weight: 962.065
• Mol file: 65296-42-6.mol

Synonyms:dihydrido(tetrahydrofuran)tris(triphenylphosphine)ruthenium(II)

Chemical Property of dihydrido(tetrahydrofuran)tris(triphenylphosphine)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of dihydrido(tetrahydrofuran)tris(triphenylphosphine)ruthenium(II)

There total 6 articles about dihydrido(tetrahydrofuran)tris(triphenylphosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

chlorohydridotris(triphenylphosphine)ruthenium(II) (55102-19-7,879374-40-0,879374-44-4,99944-74-8) + sodium methylate (124-41-4) → carbonyldihydridotris(triphenylphosphine)ruthenium(II) (22337-78-6) + dihydrido(tetrahydrofuran)tris(triphenylphosphine)ruthenium(II) (65296-42-6)

Guidance literature:

With tetrahydrofuran; In tetrahydrofuran; methanol; Ar-atmosphere; stirring in THF/MeOH=30:1 (v/v) for 0.5 h; filtration, volume reduction, crystn. on addn. of light petroleum and cooling, collection, drying (vac.);

DOI:10.1039/DT9770001546

Reference yield:

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + magnesium amalgam → hydridochlorotris(triphenylphosphine)ruthenium(II) (55102-19-7) + dihydrido(tetrahydrofuran)tris(triphenylphosphine)ruthenium(II) (65296-42-6)

Guidance literature:

With tetrahydrofuran; triphenylphosphine; In tetrahydrofuran; stirring (16 h); filtration, partial evapn., treatment with Et2O, filtration, cooling to -20°C;

DOI:10.1039/DT9790001283

Reference yield:

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) → dihydrido(tetrahydrofuran)tris(triphenylphosphine)ruthenium(II) (65296-42-6)

Guidance literature:

With tetrahydrofuran; In tetrahydrofuran; room temp.;

DOI:10.1039/DT9790001283

upstream raw materials:

chlorohydridotris(triphenylphosphine)ruthenium(II)

sodium methylate

tris(triphenylphosphine)ruthenium(II) chloride

benzophenone

Downstream raw materials:

tetrahydridotris(triphenylphosphine)ruthenium(IV)