{Ru(hydrogen)2(nitrogen)(triphenylphosphine)3}

Base Information

• Chemical Name: {Ru(hydrogen)2(nitrogen)(triphenylphosphine)3}
• CAS No.: 36620-55-0
• Molecular Formula: C₅₄H₄₇N₂P₃Ru
• Molecular Weight: 917.972
• Mol file: 36620-55-0.mol

Synonyms:

Chemical Property of {Ru(hydrogen)2(nitrogen)(triphenylphosphine)3}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Ru(hydrogen)2(nitrogen)(triphenylphosphine)3}

There total 10 articles about {Ru(hydrogen)2(nitrogen)(triphenylphosphine)3} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

chlorohydridotris(triphenylphosphine)ruthenium(II) (55102-19-7,879374-40-0,879374-44-4,99944-74-8) + potassium triethylborohydride → {Ru(hydrogen)2(nitrogen)(triphenylphosphine)3} (36620-55-0,22337-84-4)

Guidance literature:

In tetrahydrofuran; byproducts: KCl; addn. of a THF soln. of K(HBEt3) to a stirred suspension of (RuHCl(PPh3)3) in THF; stirring at room temp. for 40 h; filtration; addn. of hexane to the soln.; exclusion of air and moisture;; filtration; ppt. from benzene soln. by addn. of hexane;;

DOI:10.1021/ja00244a019

Reference yield:

{RuHCl(triphenylphosphine)3} * benzene (22493-02-3,51383-67-6) + nitrogen (7727-37-9) + triethylaluminum (97-93-8) → {Ru(hydrogen)2(nitrogen)(triphenylphosphine)3} (36620-55-0,22337-84-4)

Guidance literature:

In diethyl ether; reaction in ethereal soln.;; recrystn. from mixture of C6H6 and hexane under N2 atmosphere;;

Reference yield:

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) → {Ru(hydrogen)2(nitrogen)(triphenylphosphine)3} (36620-55-0,22337-84-4)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: N₂ / tetrahydrofuran

With N₂; In tetrahydrofuran;

DOI:10.1039/c39850001379

upstream raw materials:

chlorohydridotris(triphenylphosphine)ruthenium(II)

{RuHCl(triphenylphosphine)3} * benzene

nitrogen

triethylaluminum

Downstream raw materials:

RuHI(PPh₃)₃

{Ru(hydrogen)2(ammonia)(triphenylphosphine)3}

dichlorotris(triphenylphosphine)ruthenium(II)

ammonia