Ph₂P(CH₂)2OPh

Base Information

Chemical Name:Ph₂P(CH₂)2OPh
CAS No.:162616-45-7
Molecular Formula:C₂₀H₁₉OP
Molecular Weight:306.344
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ph₂P(CH₂)2OPh

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Technology Process of Ph₂P(CH₂)2OPh

There total 1 articles about Ph₂P(CH₂)2OPh which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 15475-27-1,4346-39-8
potassium diphenylphosphine

: 622-86-6
2-chloroethoxybenzene

: 162616-45-7
Ph₂P(CH₂)2OPh

Guidance literature:: In tetrahydrofuran; at 0 ℃;

Reference yield: 94.0%

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 162616-45-7
Ph₂P(CH₂)2OPh

: 1122510-94-4
trans-[κ1-(Ph2PC2H4OPh)2PdCl2]

Guidance literature:: In dichloromethane; (N2); std. Schlenk technique; soln. of Pd complex (1 equiv.) in CH2Cl2 was added to soln. of Ph2PC2H4OPh (2 equiv.) in CH2Cl2; after 1 h layered with hexane; elem. anal.;
DOI:10.1021/om801060m

Reference yield: 86.0%

: 14104-20-2
silver tetrafluoroborate

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 20859-51-2
1-(methylthio)-2-(diphenylphosphino)ethane

: 162616-45-7
Ph₂P(CH₂)2OPh

: cis-[κ2-(Ph2PC2H4SMe)-κ2-(Ph2PC2H4OPh)Pd](BF4)2

Guidance literature:: In dichloromethane; byproducts: 1,5-cyclooctadiene; (N2); Schlenk technique; Pd complex (1 equiv.) in CH2Cl2 added dropwise to stirred soln. of Ph2PC2H4SMe (1 equiv.) in CH2Cl2 at 24°C; after 5 min soln. of Ph2PC2H4OPh (1 equiv.) in CH2Cl2 added dropwise; stirred (1 h); AgBF4 (2 equiv.) added; after 1 h filtered through Celite; recrystd. (CH2Cl2/hexane); elem. anal.;
DOI:10.1021/om801060m