1-azido-2,4-bis[2,4-bis(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa-2,4-diazenium μ-azido-bis[hexachloridogallium(III)]

Base Information

• Chemical Name: 1-azido-2,4-bis[2,4-bis(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa-2,4-diazenium μ-azido-bis[hexachloridogallium(III)]
• CAS No.: 1176327-59-5
• Molecular Formula: C₄₈H₅₀As₂N₅*Cl₆Ga₂N₃
• Molecular Weight: 1240.99
• Mol file: 1176327-59-5.mol

Synonyms:

Chemical Property of 1-azido-2,4-bis[2,4-bis(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa-2,4-diazenium μ-azido-bis[hexachloridogallium(III)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-azido-2,4-bis[2,4-bis(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa-2,4-diazenium μ-azido-bis[hexachloridogallium(III)]

There total 2 articles about 1-azido-2,4-bis[2,4-bis(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa-2,4-diazenium μ-azido-bis[hexachloridogallium(III)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

trimethylsilylazide (4648-54-8) + 1-chloro-2,4-bis[2,4-bis(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa-2,4-diazenium tetrachloridogallate (1176327-56-2) + Gallium trichloride (13450-90-3) → 1-azido-2,4-bis[2,4-bis(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa-2,4-diazenium μ-azido-bis[hexachloridogallium(III)] (1176327-59-5)

Guidance literature:

In dichloromethane; (Ar) to soln. Ga complex in CH2Cl2 10 equiv. soln. Me3SiN3 in CH2Cl2 wasadded dropwise at -10°C over 5 min, soln. GaCl3 in CH2Cl2 was ad ded at -10°C over 10 min, soln. was warmed to room temp. and stirred for 2 days; solvent was removed in vacuo, residue was washed with n-hexane, dried invacuo and dissolved in CH2Cl2, soln. was filtered and evapd. in vacuo; elem. anal.;

DOI:10.1021/ic900821h

Reference yield:

1,3-dichloro-2,4-bis[2,4-bis-(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa-2,4-diazane (1176327-53-9,1257432-62-4) → 1-azido-2,4-bis[2,4-bis(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa-2,4-diazenium μ-azido-bis[hexachloridogallium(III)] (1176327-59-5)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: dichloromethane

In dichloromethane; toluene;

DOI:10.1021/ic900821h

upstream raw materials:

trimethylsilylazide

1-chloro-2,4-bis[2,4-bis(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa-2,4-diazenium tetrachloridogallate

Gallium trichloride

1,3-dichloro-2,4-bis[2,4-bis-(2,4,6-trimethylphenyl)phenyl]-cyclo-1,3-diarsa-2,4-diazane