Pyridine, 4-[2-(triphenylstannyl)ethyl]-

Base Information

• Chemical Name: Pyridine, 4-[2-(triphenylstannyl)ethyl]-
• CAS No.: 119210-61-6
• Molecular Formula: C25H23NSn
• Molecular Weight: 456.174
• NSC Number: 203256
• DSSTox Substance ID: DTXSID30308364
• Wikidata: Q82056208
• Mol file: 119210-61-6.mol

Synonyms:Pyridine, 4-[2-(triphenylstannyl)ethyl]-;119210-61-6;NSC203256;DTXSID30308364;NSC-203256

Chemical Property of Pyridine, 4-[2-(triphenylstannyl)ethyl]-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 457.085252
• Heavy Atom Count: 27
• Complexity: 367

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn](CCC2=CC=NC=C2)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Pyridine, 4-[2-(triphenylstannyl)ethyl]-

There total 3 articles about Pyridine, 4-[2-(triphenylstannyl)ethyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-vinylpyridine (100-43-6,329041-72-7) + triphenylstannane (892-20-6) → hexaphenylditin (1064-10-4) + {2-(4-pyridyl)ethyl}triphenyltin (119210-61-6)

Guidance literature:

In melt; stirring of 7.37 mmol triphenyltin hydride and 11 mmol 4-vinylpyridine at 100°C for 0.5 h as a melt under N2;; recrystallization from petroleum ether yields hexaphenylditin; evaporation of the mother liquor to dryness under reduced pressure; recrystallization from petroleum ether; elem. anal.;;

DOI:10.1021/om00027a029

Reference yield: 83.0%

4-vinylpyridine (100-43-6,329041-72-7) + triphenylstannane (892-20-6) → {2-(4-pyridyl)ethyl}triphenyltin (119210-61-6)

Guidance literature:

In benzene; heated at reflux for 0.5 h;;

Reference yield:

→ {2-(4-pyridyl)ethyl}triphenyltin (119210-61-6)

Guidance literature:

Triphenylstannan, 4-Vinyl-pyridin;

DOI:10.1016/S0022-328X(00)87687-1

upstream raw materials:

4-vinylpyridine

triphenylstannane

Downstream raw materials:

{2-(4-pyridyl)ethyl}diphenyltin iodide

{2-(4-pyridyl)ethyl}diphenyltin bromide

phenylmercury(II) chloride