trans-{(PPh₃)2ClPt(CO)}BF₄

Base Information

Chemical Name:trans-{(PPh₃)2ClPt(CO)}BF₄
CAS No.:34053-63-9
Molecular Formula:BF₄*C₃₇H₃₀ClOP₂Pt
Molecular Weight:869.93
Hs Code.:

trans-{(PPh<sub>3</sub>)2ClPt(CO)}BF<sub>4</sub>

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Chemical Property of trans-{(PPh₃)2ClPt(CO)}BF₄

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Technology Process of trans-{(PPh₃)2ClPt(CO)}BF₄

There total 1 articles about trans-{(PPh₃)2ClPt(CO)}BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 14104-20-2
silver tetrafluoroborate

: 10199-34-5,14056-88-3,15604-36-1
bis(triphenylphosphine)platinum(II) dichloride

: 34053-63-9,19184-24-8
trans-{(PPh₃)2ClPt(CO)}BF₄

Guidance literature:: In dichloromethane; acetone; exclusion of moisture; soln. of AgBF4 in acetone added dropwise to soln. of Pt-compd. in CH2Cl2, stirred for 2 h; filtered (Celite), Celite rinsed with CH2Cl2, soln. treated with 30 psiCO for 21 h, evapd. (vac.), solid triturated with Et2O;

Reference yield: 92.0%

: 34053-63-9,19184-24-8
trans-{(PPh₃)2ClPt(CO)}BF₄

: 870-24-6
2-chloroethanamine hydrochloride

: trans-{(PPh₃)2Pt(COCH₂CH₂NH)Cl}BF₄

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; treating a stirred suspn. of Cl(NH3CH2CH2Cl) with a 1.4 M n-hexane soln. of n-BuLi at 0°C; addn. of solid Pt-complex; stirring for 1 day at room temp.; taking to dryness (vac.); addn. of CH2Cl2; filtration; dropwise addn. of n-hexane; pptn.; filtration; washing with n-hexane; drying (vac.);

Reference yield: 75.0%

: 151-56-4,9002-98-6
ethyleneimine

: 34053-63-9,19184-24-8
trans-{(PPh₃)2ClPt(CO)}BF₄

: 870-24-6
2-chloroethanamine hydrochloride

: 10199-34-5,14056-88-3,15604-36-1
cis-dichlorobis(triphenylphosphine)platinum(II)

: trans-{(PPh₃)2Pt(COCH₂CH₂NH)Cl}BF₄

Guidance literature:: In tetrahydrofuran; addn. of aziridine to a stirred suspn. of Cl(NH3CH2CH2Cl) at 0°C; addn. of solid Pt-complex; stirring for 30 min at 0°C; stirring for 3 h at room temp.; taking to dryness (vac.); addn. of CH2Cl2; filtration; dropwise addn. of n-hexane; pptn.; filtration; washing with n-hexane; drying (vac.); elem. anal.;