NiBr(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*AsF₆^(1-) = {NiBr(P(CH₂CH₂P(C₆H₅)2)3)}AsF₆

Base Information

Chemical Name:NiBr(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*AsF₆^(1-) = {NiBr(P(CH₂CH₂P(C₆H₅)2)3)}AsF₆
CAS No.:99687-63-5
Molecular Formula:AsF₆*C₄₂H₄₂BrNiP₄
Molecular Weight:998.197
Hs Code.:

NiBr(P(CH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)3)<sup>(1+)</sup>*AsF<sub>6</sub><sup>(1-)</sup> = {NiBr(P(CH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)3)}AsF<sub>6</sub>

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Chemical Property of NiBr(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*AsF₆^(1-) = {NiBr(P(CH₂CH₂P(C₆H₅)2)3)}AsF₆

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Technology Process of NiBr(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*AsF₆^(1-) = {NiBr(P(CH₂CH₂P(C₆H₅)2)3)}AsF₆

There total 1 articles about NiBr(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*AsF₆^(1-) = {NiBr(P(CH₂CH₂P(C₆H₅)2)3)}AsF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 23582-03-8
tris(2-diphenylphosphinoethyl)phosphine

: 29935-35-1,132004-89-8
lithium hexafluoroarsenate

: 13462-88-9
nickel dibromide

: 99687-63-5
NiBr(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*AsF₆^(1-) = {NiBr(P(CH₂CH₂P(C₆H₅)2)3)}AsF₆

Guidance literature:: In ethanol; dichloromethane; under N2; addn. of a soln. of equimolar amts. of the organic ligand in CH2Cl2 to a soln. of the Ni salt in EtOH with slight excess of LiAsF6; heated at 50°C for 1h; refluxed for 6h; soln. concd., ppt washed with EtOH, Et2O, dried in vac.;;

Reference yield: 77.0%

: 99687-63-5
NiBr(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*AsF₆^(1-) = {NiBr(P(CH₂CH₂P(C₆H₅)2)3)}AsF₆

: 29935-35-1,132004-89-8
lithium hexafluoroarsenate

: 122-52-1
triethyl phosphite

: 99687-56-6
Ni(P(CH₂CH₂P(C₆H₅)2)3)((P(OCH₂CH₃)3))⁽²⁺⁾*2AsF₆^(1-) = {Ni(P(CH₂CH₂P(C₆H₅)2)3)(P(OCH₂CH₃)3)}(AsF₆)2

Guidance literature:: In ethanol; under N2; addn. of excess of phosphite to a stirred soln. of the Ni complex and slight excess of LiAsF6; stirred for 2h; ppt. washed with EtOH, Et2O, dried in vac.;; elem. anal.;;

Reference yield: 45.0%

: 99687-63-5
NiBr(P(CH₂CH₂P(C₆H₅)2)3)⁽¹⁺⁾*AsF₆^(1-) = {NiBr(P(CH₂CH₂P(C₆H₅)2)3)}AsF₆

: 29935-35-1,132004-89-8
lithium hexafluoroarsenate

: 121-45-9
phosphorous acid trimethyl ester

: Ni(P(CH₂CH₂P(C₆H₅)2)3)((P(OCH₃)3))⁽²⁺⁾*2AsF₆^(1-) = {Ni(P(CH₂CH₂P(C₆H₅)2)3)(P(OCH₃)3)}(AsF₆)2

Guidance literature:: In methanol; under N2; addn. of excess of phosphite to a stirred soln. of the Ni complex and slight excess of LiAsF6; stirred for 2h; ppt. washed with MeOH, Et2O, dried in vac.;; elem. anal.;;