diphenylmonochlorotin(IV) p-chlorobenzohydroxamate

Base Information

• Chemical Name: diphenylmonochlorotin(IV) p-chlorobenzohydroxamate
• CAS No.: 198630-99-8
• Molecular Formula: C₁₉H₁₅Cl₂NO₂Sn
• Molecular Weight: 478.95
• Mol file: 198630-99-8.mol

Synonyms:

Chemical Property of diphenylmonochlorotin(IV) p-chlorobenzohydroxamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenylmonochlorotin(IV) p-chlorobenzohydroxamate

There total 1 articles about diphenylmonochlorotin(IV) p-chlorobenzohydroxamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

diphenyltin(IV) dichloride (1135-99-5) + potassium p-chlorobenzohydroxyamate (57139-20-5) → diphenylmonochlorotin(IV) p-chlorobenzohydroxamate (198630-99-8)

Guidance literature:

In tetrahydrofuran; methanol; byproducts: KCl; molar ratio Sn : ligand = 1 : 1; mixing soln. of Sn-complex (in THF) andlignad salt (in MeOH), stirring (room temp.), refluxing (8 - 10 h, wate r bath); filtrtaion, distn. off of solvent, standing (overnight, room temp., crystn.), recrystn. (MeOH); alam. anal.;

DOI:10.1080/00945719708000166

Reference yield: 70.0%

diphenylmonochlorotin(IV) p-chlorobenzohydroxamate (198630-99-8) + sodium (Z)-4-oxopent-2-en-2-olate (1118-67-8) → diphenyltin(IV) p-chlorobenzohydroxamate * acetylacetonate (198631-11-7)

Guidance literature:

In methanol; byproducts: NaCl; stirring (room temp.), refluxing (6 - 8 h); filtration, concn. of filtrate, sepn., washing (petroleum ether), recrystn. (MeOH); elem. anal.;

DOI:10.1080/00945719708000166

Reference yield: 69.0%

diphenylmonochlorotin(IV) p-chlorobenzohydroxamate (198630-99-8) + sodium dibenzoylmethane (19269-14-8) → diphenyltin(IV) p-chlorobenzohydroxamate * dibenzoylmethanate (198631-15-1)

Guidance literature:

In methanol; byproducts: NaCl; stirring (room temp.), refluxing (6 - 8 h); filtration, concn. of filtrate, sepn., washing (petroleum ether), recrystn. (MeOH); elem. anal.;

DOI:10.1080/00945719708000166

upstream raw materials:

diphenyltin(IV) dichloride

potassium p-chlorobenzohydroxyamate

Downstream raw materials:

diphenyltin(IV) p-chlorobenzohydroxamate * salicylaldehyde

diphenyltin(IV) p-chlorobenzohydroxamate * dibenzoylmethanate

diphenyltin(IV) p-chlorobenzohydroxamate * acetylacetonate