α-fenchyltriphenyltin

Base Information

• Chemical Name: α-fenchyltriphenyltin
• CAS No.: 1110686-64-0
• Molecular Formula: C₂₈H₃₂Sn
• Molecular Weight: 487.272
• Mol file: 1110686-64-0.mol

Synonyms:

Chemical Property of α-fenchyltriphenyltin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α-fenchyltriphenyltin

There total 4 articles about α-fenchyltriphenyltin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1R,2S,4S)-exo-β-fenchyl chloride (1195-77-3,3372-12-1,90976-73-1) + triphenyltin chloride (639-58-7) → β-fenchyltriphenyltin (1110686-64-0,1110686-62-8) + α-fenchyltriphenyltin (1110686-64-0,1110686-62-8) + triphenyltin(IV) hydroxide (76-87-9)

Guidance literature:

With magnesium; In tetrahydrofuran; toluene; soln. of β-fenchyl chloride in THF wasadded to suspn. of Mg in THF,refluxed for 12 h, separated from Mg via cannula, Ph3SnCl was added; detected by 119Sn NMR;

DOI:10.1039/b819178f

Reference yield:

(1R,2S,4S)-exo-β-fenchyl chloride (1195-77-3,3372-12-1,90976-73-1) + triphenyltin chloride (639-58-7) → β-fenchyltriphenyltin (1110686-64-0,1110686-62-8) + α-fenchyltriphenyltin (1110686-64-0,1110686-62-8) + triphenyltin(IV) hydroxide (76-87-9)

Guidance literature:

With magnesium; In tetrahydrofuran; toluene; soln. of β-fenchyl chloride in THF wasadded to suspn. of Mg in THF,refluxed for 12 h, separated from Mg via cannula, Ph3SnCl was added; detected by 119Sn NMR;

DOI:10.1039/b819178f

Reference yield:

endo-2-chloro-1,3,3-trimethylbicyclo[2.2.1]heptane (847994-82-5) + triphenyltin chloride (639-58-7) → β-fenchyltriphenyltin (1110686-64-0,1110686-62-8) + α-fenchyltriphenyltin (1110686-64-0,1110686-62-8) + triphenyltin(IV) hydroxide (76-87-9)

Guidance literature:

With magnesium; In tetrahydrofuran; toluene; soln. of α-fenchyl chloride in THF wasadded to suspn. of Mg in THF, refluxed for 12 h, separated from Mg via cannula, Ph3SnCl was added; detected by 119Sn NMR;

DOI:10.1039/b819178f

upstream raw materials:

(1R,2S,4S)-exo-β-fenchyl chloride

triphenyltin chloride

endo-2-chloro-1,3,3-trimethylbicyclo[2.2.1]heptane

Refernces