3,6-dibromo-9-butyl-9H-carbazole

Base Information

• Chemical Name: 3,6-dibromo-9-butyl-9H-carbazole
• CAS No.: 121602-03-7
• Molecular Formula: C16H15Br2N
• Molecular Weight: 381.11
• Hs Code.: 2933990090
• European Community (EC) Number: 801-581-0
• DSSTox Substance ID: DTXSID50479186
• Nikkaji Number: J1.959.108E
• Wikidata: Q82313138
• Mol file: 121602-03-7.mol

Synonyms:3,6-dibromo-9-butyl-9H-carbazole;121602-03-7;3,6-dibromo-9-butylcarbazole;9H-Carbazole, 3,6-dibromo-9-butyl-;SCHEMBL435200;DTXSID50479186;YTQDAHGLEKIAOU-UHFFFAOYSA-N;MFCD22052128;AKOS025393526;SS-2581;CS-0338637;A921756

Chemical Property of 3,6-dibromo-9-butyl-9H-carbazole

Chemical Property:

• PSA: 4.93000
• LogP: 6.11960
• XLogP3: 5.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 380.95508
• Heavy Atom Count: 19
• Complexity: 283

Purity/Quality:

97% ^*data from raw suppliers

3,6-Dibromo-9-butyl-9H-carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCN1C2=C(C=C(C=C2)Br)C3=C1C=CC(=C3)Br

Technology Process of 3,6-dibromo-9-butyl-9H-carbazole

There total 6 articles about 3,6-dibromo-9-butyl-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-bromo-butane (109-65-9) + 3,6-dibromo-9H-carbazole (6825-20-3) → 3,6-dibromo-(N-n-butyl)carbazole (121602-03-7)

Guidance literature:

3,6-dibromo-9H-carbazole; With sodium hydroxide; In acetone; at 60 ℃; for 0.5h; Inert atmosphere;

1-bromo-butane; In acetone; Reflux; Inert atmosphere;

DOI:10.1021/acs.orglett.6b02500

Reference yield: 94.0%

9-butyl-9H-carbazole (1484-08-8) → 3,6-dibromo-(N-n-butyl)carbazole (121602-03-7)

Guidance literature:

With N-Bromosuccinimide; In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.jphotochem.2014.09.007

Reference yield: 85.0%

1-bromo-butane (109-65-9) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 3,6-dibromo-(N-n-butyl)carbazole (121602-03-7)

Guidance literature:

9H-carbazole; With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 0.5h; Schlenk technique; Inert atmosphere;

1-bromo-butane; In N,N-dimethyl-formamide; at 25 ℃; for 5h; Schlenk technique; Inert atmosphere;

With N-Bromosuccinimide; In N,N-dimethyl-formamide; at 25 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.tetlet.2019.151340

upstream raw materials:

9-butyl-9H-carbazole

1-bromo-butane

3,6-dibromo-9H-carbazole

9H-carbazole

Downstream raw materials:

3,6-bis(dimesitylboryl)-N-butyl-carbazole

4-{6-[5'-(N-butylcarbazole-3-yl)-2,2'-bithiophene-5-yl]-N-butylcarbazole-3-yl}-styrene

4-[6-(N-butylcarbazole-3-yl)-N-butylcarbazole-3-yl]-styrene

4-[6-(4,4,5,5-tetramethyl-1,3,2-dioxaboroyl)-N-butylcarbazole-3-yl]-styrene